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p-hydroxybenzaldehyde?
From p-nitrotoluene...
[list][*]Reduction/oxidation with sodium disulfide or polysulfide to p-amino ...
28-4-2011 at 07:01
by: dean stark
Tricyclodecenyl ester to (di)cyclopentadiene via elimination?
I'm thinking there are two ways to (di)cyclopentadiene from e.g. tricyclodecenyl acetate...
1. Py ...
22-4-2011 at 06:26
by: dean stark
Question about this reaction on a compound with methylenedioxy group.
The md group is prone to cleavage when subject to acid, but I'm not sure how sensitive it is with re ...
22-4-2011 at 06:02
by: dean stark
Stereoselective N-alkylation of ketimines
That makes sense. I guess I figured that since adding hydrogen across the double bond (to both C and ...
11-4-2011 at 14:39
by: dean stark
N-tosyl-(S)-2-methylaziridine from (2S,3R)-threonine?
After numerous edits, I think I've answered my own question. Correct me if I'm rong...
The usual ...
11-4-2011 at 03:46
by: dean stark
Stereoselective N-alkylation of ketimines
Possibly an odd question, but...
It's pretty common to see enantiopure alpha-methylbenzylamine be ...
11-4-2011 at 03:27
by: dean stark
Ozonelabs-Synthesis of Tetrahydrobenzodipyran
I think I found the paper you were talking about Nicodem - "The Synthesis of 5-Substituted 2,3-Dihyd ...
11-4-2011 at 02:19
by: dean stark
Ozonelabs-Synthesis of Tetrahydrobenzodipyran
Can anyone comment on the likelyhood of using magnesium exchange via isopropylmagnesium halide inste ...
8-4-2011 at 06:25
by: dean stark
Catechol preparation
Thanks Nicodem.
The Fries rearrangement in the paper I mentioned seems to be selective to some de ...
19-3-2011 at 03:00
by: dean stark
Catechol preparation
Pretty sure the ortho-Fries rearrangement of Aspirin IS 3-acetylsalicylic acid (unless I'm getting t ...
18-3-2011 at 04:35
by: dean stark
Aspirin
Okay, so not terribly straightforward but...
Aspirin to 3-acetylsalicylic acid via [url=https://w ...
18-3-2011 at 00:55
by: dean stark
Stator and back-EMF
A nod to Stasis, obsessed_chemist, and kmno4.
The Stator idea is f**king cool.
[url=http://2ma ...
18-3-2011 at 00:38
by: dean stark
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