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Rotation of atoms around single/double/triple bonds
Many times molecules are referred as cis/trans in newmann projections. This may contribute to confu ...
25-4-2019 at 23:36
by: qt314
piperazine hexahydrate from citrate salt
You should add base to 2 pH units above the pkb of piperazine. Then extract with non polar and evapo ...
25-4-2019 at 23:32
by: qt314
Rotation of atoms around single/double/triple bonds
Its also very straightforward to visualize if you draw the actual atomics orbitals and see with logi ...
25-4-2019 at 03:35
by: qt314
Pd/C (+H2) Catalyzed Reductive Amination of Aliphatic Ketones
I would like to report my success with palladium catalyzed reductive aminations of phenylacetones us ...
25-4-2019 at 03:29
by: qt314
The synthesis of primairy amines -> NH2OH.HCl + ketone
Ketoximes may be prepared with ease using hydroxylammonium salt and sodium acetate as base in reflux ...
22-4-2019 at 21:16
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
--update--

I followed the progress of reaction on tlc (MeOH/Conc. Ammonia, 100:1) every hour inst ...
28-1-2019 at 10:37
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
[rquote=593418&tid=136304&author=S.C. Wack][rquote=591500&tid=136304&author=qt314]Du ...
28-1-2019 at 01:55
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
[rquote=592814&tid=136304&author=clearly_not_atara]What kind of mineral acid are you using? ...
27-1-2019 at 02:03
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
[rquote=591633&tid=136304&author=unionised]Just a thought; O2 goes through rubber quite well ...
26-1-2019 at 23:01
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
Oh, forgot to mention - I tried cth with ammonium formate and pd/c (6eq, 20% w/w respectively) for ...
25-1-2019 at 07:13
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
TAB witg CoCl2 should work though I haven't tried yet. Or do you claim it works without the cobalt?
25-1-2019 at 07:06
by: qt314
3,4,5-trimethoxyphenylacetonitrile hydrogenation problems
Hello. I havent posted here in a *very very* long time but find myself in need of help ...

I have ...
25-1-2019 at 05:22
by: qt314

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