Sciencemadness Discussion Board

Transition Metal Oxidation Number

lacrima97 - 15-2-2006 at 18:49

How is CuO formed, when Cu only has 1 electron (4s1) and oxygen needs to take 2 electrons in (2s2 2p4)?

To me it seems that Cu would have an oxidation number of +1, but I don't think that is the case. Is an electron donated from the 3d orbital? If so, would the 3d10 become 3d9?

guy - 15-2-2006 at 21:07

It takes the electron from 4s and 3d. It CAN have an oxidation number of +1. The thing is that the 4s and 3d are basically degenerates (same energy) so it can remove the electrons from 4s and 3d.

lacrima97 - 16-2-2006 at 05:48

Ohhhh. I didn't know that the 4s and 3d had the same energy...Well, I figured it must be something like that. Thanks for the help.