Colourless gas from making copper nitrate

Just a curiosity question, well two actually.

I wanted some copper nitrate so added freshly stripped thick copper wire, to 50% Nitric Acid. To this I added ~100ml of cold water into the flask. I was aware that it might take a while to react and for my purpose this was intended.

On top of the flask i placed a small round bottomed one parlty filled with cold water, the thinking being any Nitrogen dioxide would condense on the bottom and drip back into the flask.

Fist day i got very few bubbles and a slight blue tinge to the flask, this was ok i was not in a hurry. Second day the water had reached room temp (~16c) and a little more bubbling.

I had intended to move the flask that night but forgot....

In the morning I went to look and as i entered the room i could smell the nasty almost bleach like smell. Not bad enough to make you cough or anything but enough to make me move it . ANYWAY the flask has alot of tiny bubbles in and still plenty of copper, it hasnt gone the deep blue i normally see. Instead its more a turquoise/green colour.

I assume this is just a hydration state as the acid was fairly strong and it hasnt finished reacting, but now the question.

The flask has small gaps around the round bottom one i put on top, i know there is a gas because i can see the tiny bubbles and i can smell it. As soon as i lift off the small flask the neck of the main flask fills with Brown Nitrogen Dioxide.

If i place the flask back on then the gas slowly clears to colorless again.

The flask is slightly warm (~19c) room is around (~14c), I can see alot of tiny bubbles in the flask to the extent this might be making the colour different, but what is the colourless gas?

Smells like nitrogen Dioxide just dosnt look at all brown until you lift the top flask off.

Sorry if its a stupid question but i am curious why the gas is clear until you lift the top. the neck isnt gas tight so i would assume air is getting in anyway.

Quote: Originally posted by NEMO-Chemistry

well having moved it its gone from the blue colour a bit like copper hydroxide (could have been all the timy cuccles making the colour) to a really deep clear emerald green colour!! the copper is slowly disolcing and a clear gas still evolving. any idea why the deep emerald green colour?? I was expecting a deep blue colour???

Quote: Originally posted by DraconicAcid

Quote: Originally posted by NEMO-Chemistry   well having moved it its gone from the blue colour a bit like copper hydroxide (could have been all the timy cuccles making the colour) to a really deep clear emerald green colour!! the copper is slowly disolcing and a clear gas still evolving. any idea why the deep emerald green colour?? I was expecting a deep blue colour??? It will be blue once you dilute it.

Quote: Originally posted by CharlieA

Just curious, but why did you expect nitrogen dioxide, mp ~ -11*C, to condense on your flask of cold water?

I didnt exactly, i was a little lazy in my description. Normally when i do this i get brownish liquid droplets on the bottom of the water flask, I assume this contains Nitrogen dioxide.

@Woelen

that is kind of exactly what I see in the flask, its a long necked flat bottomed round flask. The gas is clear but as soon as I remove the top flask it goes brown. Pretty neat actually .

I also found if I stick a shovtwave UV lamp on top the flask the bubbles increase...but I guess everyone except me knew that

dosnt help i took the pic on a blue top!! but i arowed the kind of green the flask has gone. loads of copper left so i assume its about out of water. bubbles have stopped.

I am tempted to put some in a desiccator and see if i get any crystals and if so what colour etc

Quote: Originally posted by NEMO-Chemistry

dosnt help i took the pic on a blue top!! but i arowed the kind of green the flask has gone. loads of copper left so i assume its about out of water. bubbles have stopped. I am tempted to put some in a desiccator and see if i get any crystals and if so what colour etc

ok something went wrong, i got tiny green sugar grain type crystals, the pic didnt come out well. As soon as you lift the desiccator they go blue and mush, except a few that seem to stay green???

No real question just adding some observations as i loose notes .