Sciencemadness Discussion Board

1,3-dimethylurea ( and its abilities )

roamingnome - 12-7-2007 at 14:27

good pictures to view here

http://www.organic-chemistry.org/abstracts/lit1/262.shtm

Abstract

Neat non-volatile amines react efficiently with various aromatic aldehydes in the absence of any catalyst or solvent, to give imines after a reaction time of eight minutes under microwave irradiation. 1,3-dimethylurea dispersed on montmorillonite K10 is used as an methylamine precursor.

L. Paquin, J. Hamelin, F. Texier-Boullet, Synthesis, 2006, 1652-1656


non-volatile amines.... hmmm like alanine maybye


Two questions i raise are

1)we arent these folks worried about water forming and spoiling the imine formation?

possible answer its boiled away

2) 1,3-dimethylurea ?

possible answer because its the new nitromethane