Sciencemadness Discussion Board

Hexamine Nitration

FHL - 22-12-2007 at 03:36

Could any one tell me what is the heat of reaction making concentrated Hexamine Nitrate? I want to add one mol HNO3 into a one mol Hexamine solution. I want to calcute the heat of reaction and final temperature. any comments are much welcome.

zeppelin69 - 22-12-2007 at 07:25

Dependng on the concentration of your acid, you will more than likely end up with the dinitrate, HDN. I cannot give you any information on heat of formation, but to calculate the heat given off in a reaction, you will need to use a calorimeter.

FHL - 22-12-2007 at 15:35

nitric acid is 53%. I first dissolve Hexamine into the water to make PH 8.5. then I add NA53% gradually to prevent Hexamine dinitrate formation. I only need Hexamine nitrate.

chemrox - 22-12-2007 at 19:55

I think this will make Me-NH2.HNO3

AndersHoveland - 29-5-2013 at 12:41

I had an idea for making hexamine dinitrate without the nitric acid. Just mix 1 molar equivalent of hexamine with 4 equivalents of NH4NO3 and 6 molar equivalents of formaldehyde.
Hexamine disassociates in water to some extent back to CH2O and NH3, the equilibrium preferring condensation towards hexamine.

papaya - 29-5-2013 at 12:57

There're people, who melt AN with hexamine which gives some HE, I've heard a lot of ammonia gas is produced, may it be HDN is formed in this reaction?