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clearly_not_atara
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Organozinc species in THF react slowly with air but do not catch fire ("slow absorption"):
https://www.sciencedirect.com/science/article/pii/0040403995...
I assume that acetonitrile organozinc reagents behave similarly. So the answer is yes an inert atmosphere is certainly required for the Blaise
reaction which happens additionally at high temperature.
[Edited on 04-20-1969 by clearly_not_atara]
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JJay
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Fun stuff: https://www.youtube.com/watch?v=EmkBH-ncG1Y
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DraconicAcid
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I'm surprised grignards are stable in acetonitrile. I had thought that it was possible to deprotonate it.
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
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JJay
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I imagine that the reaction between vanillyl magnesium chloride and acetonitrile followed by acid hydrolysis produces a nice-smelling ketone.
Edit: Oh never mind, that won't work.
[Edited on 20-12-2017 by JJay]
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zed
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Hydrogenation of Acetonitrile, could be one of the better ways to make Di-Ethyl Amine.
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clearly_not_atara
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Since when are Grignards stable in acetonitrile?
[Edited on 04-20-1969 by clearly_not_atara]
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