DubaiAmateurRocketry
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(C2N8O4) TTTO has been synthesized, its density remains unreported, and its yeild is 1%
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.2016056...
right, i actually missed this paper somehow.
Anyways, below is the synthesis of TTTO.
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Bert
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Mood: " I think we are all going to die. I think that love is an illusion. We are flawed, my darling".
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Well, that looks promising. Or scary, can't decide which.
If any could provide a pdf of the paper to upload here? I'll be asking in references as well.
[Edited on 6-20-2018 by Bert]
Rapopart’s Rules for critical commentary:
1. Attempt to re-express your target’s position so clearly, vividly and fairly that your target says: “Thanks, I wish I’d thought of putting it
that way.”
2. List any points of agreement (especially if they are not matters of general or widespread agreement).
3. Mention anything you have learned from your target.
4. Only then are you permitted to say so much as a word of rebuttal or criticism.
Anatol Rapoport was a Russian-born American mathematical psychologist (1911-2007).
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wg48
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Quote: Originally posted by Bert  | Well, that looks promising. Or scary, can't decide which.
If any could provide a pdf of the paper to upload here? I'll be asking in references as well.
[Edited on 6-20-2018 by Bert] |
Attachment: tttoklenov2016.pdf (985kB)
This file has been downloaded 458 times
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roXefeller
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Is this like the Bose Einstein condensate of EM? I once drew the simple azide group for a friend with some knowledge of chemistry from long ago. He
asked if it was really possible to have so many nitrogen atoms bonded, I replied "with some difficulty". This TTTO might make him think we're just
making stuff up.
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Fulmen
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Nah, compared to "Azidoazide azide" (1‐diazidocarbamoyl‐5‐azidotetrazole, C2N14) it looks almost tame by comparison.
We're not banging rocks together here. We know how to put a man back together.
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Tsjerk
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Haha, that stuff is crazy, I got the full article through sci-hub; they make this nitrogen compound by getting hydrazine out of the molecule
[Edited on 21-6-2018 by Tsjerk]
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wg48
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If you mean this
Yes thats a lot of N and not much C for a compound.
I wonder if the rings could be coupled in to a larger olgomer attached to an antibody that recognises say cancer cells. Then triggered by a
conformational change in the antibody when it couples to the cancer cell the olgomer detonates and blows a hole in the cell killing it. Yes just wild
speculation but the idea of blowing up cancer cells appeals to my sense of revenge LOL
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j_sum1
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Nice little (humorous) read on azidoazide_azides
http://blogs.sciencemag.org/pipeline/archives/2013/01/09/thi...
And if you enjoyed that there is also 1,1′-Azobis-1,2,3-triazole -- eight nitrogens in a row.
http://blogs.sciencemag.org/pipeline/archives/2010/10/14/who...
While you are at it, you could try Hexanitrohexaazaisowurtzitane
http://blogs.sciencemag.org/pipeline/archives/2011/11/11/thi...
Derek Lowe has quite a way with words.
[edit]
@wg48
That's a lovely looking C6N20. I am not going anywhere near any of these. I'm pretty sure they all go bang quite nicely.
[Edited on 21-6-2018 by j_sum1]
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Tsjerk
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It is the compound in this article
Attachment: azido.pdf (403kB)
This file has been downloaded 398 times
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DubaiAmateurRocketry
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Here are some interesting 1,2,3,4-tetrazine dioxides that very possibly could be synthesized.
[1] Frumkin, A., Churakov, A., Strelenko, Y., Kachala, V., & Tartakovsky, V. (1999). Synthesis of 1,2,3,4-Tetrazino[5,6-f]benzo-1,2,3,4-tetrazine
1,3,7,9-Tetra-N-oxides. Organic Letters, 1(5), 721-724. doi:10.1021/ol990713q
https://pubs.acs.org/doi/abs/10.1021/ol990713q
[2] Klapötke, Thomas M. et al. "The Synthesis And Energetic Properties Of 5,7-Dinitrobenzo-1,2,3,4-Tetrazine-1,3-Dioxide (DNBTDO)." Propellants,
Explosives, Pyrotechnics 37.5 (2012): 527-535. Web. 22 June 2018.
https://onlinelibrary.wiley.com/doi/full/10.1002/prep.201100...
I can upload a the hypothesized synthesis scheme but it would just be the same as the references.
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