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Author: Subject: What to do with unknown copper waste?
Draeger
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[*] posted on 14-3-2020 at 06:19
What to do with unknown copper waste?


So, from the experiment I did a while ago, I still have some copper waste left. I had thought that it was all copper hydroxide and basic copper carbonate. So, I added acetic acid to covert it all to copper acetate so that I finally had generally the same product.

Well, that didn't end up working. A lot of it converted to copper acetate, but a lot of it stayed as an insoluble solid, even after adding distilled water. Thus, I am now stuck with some copper acetate and unknown blue waste.

What do I do with this?

And, for the future, what do I do with unknown waste in general?




Collected elements:
Al, Cu, Ga, C (coal), S, Zn, Na

Collected compounds:

Inorganic:
NaOH; NaHCO3; MnCl2; MnCO3; CuSO4; FeSO4; aq. 30-33% HCl; aq. NaClO; aq. 9,5% ammonia; aq. 94-96% H2SO4; aq. 3% H2O2

Organic:
citric acid, sodium acetate, sodium citrate, petroleum, mineral oil
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stephill92
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[*] posted on 14-3-2020 at 07:20


You could probably just put it in a container and save it or just take it to a chemical waste disposal since you know that it contains copper. As for other waste, I just try to save all the stuff I can't pour down the drain if it's inorganic, and for organics I just try to evaporate or burn them off.
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Draeger
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[*] posted on 14-3-2020 at 09:17


Quote: Originally posted by stephill92  
You could probably just put it in a container and save it or just take it to a chemical waste disposal since you know that it contains copper. As for other waste, I just try to save all the stuff I can't pour down the drain if it's inorganic, and for organics I just try to evaporate or burn them off.

Okay. Thanks.




Collected elements:
Al, Cu, Ga, C (coal), S, Zn, Na

Collected compounds:

Inorganic:
NaOH; NaHCO3; MnCl2; MnCO3; CuSO4; FeSO4; aq. 30-33% HCl; aq. NaClO; aq. 9,5% ammonia; aq. 94-96% H2SO4; aq. 3% H2O2

Organic:
citric acid, sodium acetate, sodium citrate, petroleum, mineral oil
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anti
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[*] posted on 14-3-2020 at 10:39


Do electrolysis with lead dioxide anode to plate out the copper out of your acetate.
The blue stuff could be any of the following :
Copper Oxychloride
Copper Carbonate
Copper(I) Chloride
ALL ARE INSOLUBLE
Tho the carbonate should have reacted with the acetic acid. Try adding more.


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garphield
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[*] posted on 14-3-2020 at 11:18


Couldn't you just add sodium hydroxide or carbonate to precipitate out the copper as the hydroxide/oxide/carbonate?

[Edited on 14-3-2020 by garphield]
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