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Author: Subject: Acylal and "ketylal" properties
njl
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[*] posted on 1-2-2021 at 07:22
Acylal and "ketylal" properties


Can anyone link any literature regarding the synthesis and reactivity of "Acylals" and "Ketylals" (geminal diesters/dicarboxylates)? They seem like they would be useful reagents but I can find very little information on acylals (aldehyde derivatives) and no information on "ketylals" (ketone derivatives).
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njl
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[*] posted on 2-2-2021 at 06:32


Bump because this is cool :P

I found one paper that has some practical info:
https://insa.nic.in/writereaddata/UpLoadedFiles/PINSA/Vol68A...

[Edited on 2-2-2021 by njl]
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DraconicAcid
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[*] posted on 2-2-2021 at 14:01


I'm pretty sure I've seen something about cinnamaldehyde diacetate somewhere....

https://pubs.acs.org/doi/10.1021/ja01675a014

[Edited on 2-2-2021 by DraconicAcid]




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UC235
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[*] posted on 2-2-2021 at 18:29


Here's a prep of a benzylidene diacetate: http://orgsyn.org/Content/pdfs/procedures/cv2p0441.pdf
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