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Author: Subject: terephthalic acid ---> benzoic acid
Lithium
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[*] posted on 2-3-2012 at 22:06
terephthalic acid ---> benzoic acid


hello

i am wondering if you could remove one carboxyl group from terephthalic acid to make benzoic acid. what would be the condition this rxn would take place in? if this rxn took place at reasonable temps, pressures,etc, then this would be my source of the benzene ring.:)

Li

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Brominator
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[*] posted on 3-3-2012 at 04:07


I think it would be very hard if at all possible to selectivly decarboxylate the phthalic acid and even if you could the rxn would probally go on to decarboxylate the benzoic acid forming benzene.
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[*] posted on 3-3-2012 at 07:51


I would have to agree with Brominator. Also, terephthalic acid is a lot more expensive and less widely available than benzoic acid . . . unless you are just doing it on a small scale to prove a point, I would just buy some of the latter off eBay very cheaply as a food preservative or something.



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Lithium
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[*] posted on 3-3-2012 at 12:30


i can get lots of terephthalic acid from breaking down pet bottles.

i have no source of benzoic acid

is there any way to turn it into salicylic acid, phenol, benzene etc? i just need something more commonly used than this chem

Li

[Edited on 3-3-2012 by Lithium]
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AirCowPeaCock
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[*] posted on 3-3-2012 at 17:08


Read two posts above.



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