Thanatops1s
Hazard to Self
Posts: 54
Registered: 24-6-2013
Member Is Offline
Mood: No Mood
|
|
How to tell when HNO3 distillation is done
How to tell when it's time to call it quits, for example when production slows to a drop every X number of seconds? I just want to make sure I'm
getting the most out of my reagents.
|
|
|
bfesser
|
Thread Moved
3-9-2013 at 10:09 |
Pyro
International Hazard
Posts: 1305
Registered: 6-4-2012
Location: Gent, Belgium
Member Is Offline
Mood: No Mood
|
|
just keep heating until the temperature read on the thermometer goes over the BP of HNO3, also the production of NO2 will cease.
all above information is intellectual property of Pyro.  |
|
|
Pulverulescent
National Hazard
Posts: 793
Registered: 31-1-2008
Member Is Offline
Mood: Torn between two monikers ─ "hissingnoise" and the present incarnation!
|
|
| Quote: | | . . . just keep heating until the temperature read on the thermometer goes over the BP of HNO3, also the production of NO2 will cease.
|
HNO3 boils @~83°C but distills from H2SO4 @ between 90 and 121°C!
When finished, the temp. will start to rise fairly quickly and heating may then be stopped . . .
"I know not with what weapons World War III will be fought, but World War IV will be fought with sticks and stones"
A Einstein
|
|
|
eidolonicaurum
Hazard to Self
Posts: 71
Registered: 2-1-2014
Location: Area 51
Member Is Offline
Mood: Hydric
|
|
I wait until a drop every 5 seconds or so. Chances are, when the distillate is not coming over very quickly anymore, anything left in the flask is
removing, unless its very precious. Ie. I just get bored, and stop when its about done as above.
|
|
|
Metacelsus
International Hazard
Posts: 2531
Registered: 26-12-2012
Location: Boston, MA
Member Is Offline
Mood: Double, double, toil and trouble
|
|
On distillations such as this, I wait until the temperature in the still head peaks and then starts to decrease. This usually signifies the end of
vapor production. Patience is key. However, this only works with fractions far in boiling point (e.g. nitric and sulfuric acids).
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
