physics inclination
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interesting aluminum complex anions
So I just found out that aluminum can form complex anions with high-oxygen anions, including perchlorate and nitrate:
https://en.wikipedia.org/wiki/Hexanitratoaluminate
https://en.wikipedia.org/wiki/Hexaperchloratoaluminate
I also searched the forums and didnt see any previous mention of either of these compounds, so I hope others find this new and interesting. They seem
like powerful oxidizer anions, so it would be especially interesting if they could form a salt with cation complexes, for instance
tetramine-copper(ii) hexanitratoaluminate.
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DraconicAcid
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It's possible, but they're going to be extremely water-sensitive (you'll note that they're made in liquid SO2). The only water-stable aluminum-based
complex ion I can think of is [Al(OH)4]-. The oxalato and hexafluoro- complexes may be water-stable, but I don;t have a cite off the top of my head.
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
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PHILOU Zrealone
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(NH4)3Al(ClO4)6 was spoken about into an energetic tread
PH Z (PHILOU Zrealone)
"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
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