Difference between revisions of "Aniline"

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===Disposal===
 
===Disposal===
Aniline can be destroyed by oxidizing it with Fenton's reagent.
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Due to aniline's high flash point (70 °C), burning it in not a (good) option, as heating it to achieve the flash point will release lots of unpleasant and highly toxic aniline vapors. You can however, dilute it in a more flammable solvent and burn it in this form. Since some aniline will escape, it's mandatory to do this '''outside'''.
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Aniline can be destroyed by adding it dropwise in a fresh solution of Fenton's reagent. Since the oxidation will aerosolize a small amount of aniline, this is best done outside. Since aniline has a strong and unpleasant smell, '''do not do this indoors'''!
  
 
==References==
 
==References==

Revision as of 18:05, 16 June 2016

Aniline
Names
IUPAC name
Phenylamine
Other names
Aminobenzene
Benzenamine
Benzamine
Phenylamine
Identifiers
Jmol-3D images Image
Properties
C6H5NH2
Molar mass 93.13 g/mol
Appearance Colorless to yellow liquid
Density 1.0217 (at 20 °C)
Melting point −6.3 °C (20.7 °F; 266.8 K)
Boiling point 184.13 °C (363.43 °F; 457.28 K)
Miscible
Vapor pressure 0.6 mmHg (20 °C)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Aniline, also known as aminobenzene or phenylamine is an aromatic organic compound, the simplest aromatic amine. It has the chemical formula C6H7N or more convenient C6H5NH2.

Properties

Chemical

Aniline can be oxidized with potassium permanganate to nitrobenzene. This reaction is the opposite of aniline's synthesis.

Physical

Aniline is a colorless liquid with a strong ammonia or fish-like odor. It is miscible with water and most organic solvents.

Availability

Aniline is sold by various chemical suppliers.

Preparation

There are several ways to make aniline. The most common way involves the reduction of nitrobenzene with hydrogen in the presence of a metal catalyst.

Another method of obtaining aniline is through the destructive distillation of Indigo.

Projects

  • Make trinitroaniline

Handling

Safety

Aniline is toxic in large quantities and it's best to avoid being exposed to it for too long.

Storage

Aniline should be stored in closed bottles, away from any source of ignition and copper alloys. Due to its foul smell, it's best to keep it in a separate cabinet.

Disposal

Due to aniline's high flash point (70 °C), burning it in not a (good) option, as heating it to achieve the flash point will release lots of unpleasant and highly toxic aniline vapors. You can however, dilute it in a more flammable solvent and burn it in this form. Since some aniline will escape, it's mandatory to do this outside.

Aniline can be destroyed by adding it dropwise in a fresh solution of Fenton's reagent. Since the oxidation will aerosolize a small amount of aniline, this is best done outside. Since aniline has a strong and unpleasant smell, do not do this indoors!

References

Relevant Sciencemadness threads