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What is it about basification that causes layer separation?
Hmmm this is what I thought, but I did just read somewhere that adding an organic-water miscible sol ...
7-1-2015 at 05:14
by: Leben
What is it about basification that causes layer separation?
Why does adding sodium hydroxide cause layer separation among water and solvents that it would usual ...
31-12-2014 at 21:16
by: Leben
What is the mechanism for catalytic cleavage of ethers by Lewis Acid's?
[rquote=375510&tid=53345&author=deltaH]You missed the note in the link in regards to the sul ...
7-12-2014 at 04:00
by: Leben
What is the mechanism for catalytic cleavage of ethers by Lewis Acid's?
[rquote=375506&tid=53345&author=forgottenpassword][rquote=375504&tid=53345&author=Le ...
7-12-2014 at 03:41
by: Leben
What is the mechanism for catalytic cleavage of ethers by Lewis Acid's?
[rquote=375498&tid=53345&author=deltaH][rquote=375495&tid=53345&author=Leben]I under ...
7-12-2014 at 03:05
by: Leben
What is the mechanism for catalytic cleavage of ethers by Lewis Acid's?
I understand how the reaction works for mineral/halide acids...

But how does it work for Lewis A ...
7-12-2014 at 01:46
by: Leben
Anyone ever use high shear mixers for homogeneous reactions?
I just discovered about these recently. They have a very small spin-knob and spin up to 8000-35000 R ...
21-11-2014 at 15:24
by: Leben
Ideas for polymers that become solvent resistant after polymerization?
I forgot what page I was looking at, but Divinylbenzene + Styrene + a photointiator seems to be a re ...
16-11-2014 at 14:17
by: Leben
Ideas for polymers that become solvent resistant after polymerization?
I thought Ion Exchange Resins were used for electrochemistry? Does seem like we are talking about th ...
16-11-2014 at 13:55
by: Leben
Ideas for polymers that become solvent resistant after polymerization?
I was planning to create catalytically active solid surfaces. I thought of the idea the other day an ...
16-11-2014 at 13:12
by: Leben
Ideas for polymers that become solvent resistant after polymerization?
I've been doing some hobby research into material science and polymer blends. I've been researching ...
16-11-2014 at 11:45
by: Leben
Idea for homeade makeshift microwave reactor...thoughts??
Dr.Bob,

Those are interesting comments you make. In scavenging my Universities research database, ...
30-10-2014 at 22:30
by: Leben
Idea for homeade makeshift microwave reactor...thoughts??
ziqquratu

You may be correct that it is technically a thermal effect, in that energy is being di ...
27-10-2014 at 08:29
by: Leben
Idea for homeade makeshift microwave reactor...thoughts??
[rquote=358366&tid=41293&author=ziqquratu]
As for the mechanism behind the reaction... more ...
26-10-2014 at 20:40
by: Leben
Idea for homeade makeshift microwave reactor...thoughts??
I've always wanted a microwave reactor that didn't cost an arm and a leg.... some reactions can be d ...
26-10-2014 at 15:14
by: Leben
Microwave generator for small scale chemistry?
I've seen lots of interesting reactions that utilize microwave catalysis to achieve some incredible ...
27-9-2014 at 12:01
by: Leben
Steam Distillation vs Sohxlet Extraction... difference in nature of compounds recovered?
I'm thinking of going after some essential oils in various herbs, spices, vegetables, and so on.

...
25-9-2014 at 10:40
by: Leben
Ideas for must have chemicals!
It really depends on the nature of your reactions. I'm willing to bet if you buy 90% of the above st ...
23-9-2014 at 14:01
by: Leben
How stable are nitronate salts in solution?
The only information I can find about the shock-explosive capacity of nitronate salts has talked abo ...
16-9-2014 at 15:53
by: Leben
Cryogenic/Low temperature solvent resistant liquid pumps?
I'm not too up to date on pump terminology. Magnetic Drive pumps are considered a type of centrifuga ...
14-9-2014 at 17:31
by: Leben
Cryogenic/Low temperature solvent resistant liquid pumps?
Can anyone suggest a good one that can handle superchilled (-80 degree) solvents? Most of the sites ...
13-9-2014 at 06:35
by: Leben
When does a person cross over from being an Amateur Chemist, to a Professional/Normal Chemist?
That does seem to be the definition most people around here consider, even though it comes in direct ...
11-9-2014 at 12:00
by: Leben
When does a person cross over from being an Amateur Chemist, to a Professional/Normal Chemist?
This has been on my mind for a while.

This forum is targeted towards "amateur experimentalism", ...
11-9-2014 at 11:07
by: Leben
Solvents for Sodium Borohydride - why is methanol often included even with non-reactive polar aprotic solvents to dissolve the B
[rquote=344167&tid=33217&author=DJF90]THF does not dissolve sodium borohydride, but you can ...
4-9-2014 at 17:06
by: Leben
Safely distilling THF?
I have no plans to distill to dryness. The most distilling I will be doing of this THF is to distill ...
4-9-2014 at 17:03
by: Leben
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