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Capsazepine Synthesis
CuReUS, I just thought that something has changed. BTW I'm not laughing at other people's synthesis ... |
7-5-2017 at 08:49
by: Alice |
Capsazepine Synthesis
Assured Fish, thanks for the pics. Now as you can see, in the second pic, there is a carbon vanishin ... |
7-5-2017 at 04:50
by: Alice |
Two depictions of the same molecule.
[quote]So for benzene, there are 9 single sigma bonds and three double bonds using pi bonds I know t ... |
6-5-2017 at 10:41
by: Alice |
Two depictions of the same molecule.
Not sure what your problem is. For freely rotable bonds it doesn't matter how it's drawn. Benzene do ... |
6-5-2017 at 07:43
by: Alice |
Capsazepine Synthesis
Would be nice (and probably would bring more resonance) if you would provide a scheme containing the ... |
6-5-2017 at 01:53
by: Alice |
Why is glacial acetic acid needed in HOCl-oxidation of sec.OH?
Rethinking the mechanism, it is indeed unlikely the alcohol is protonated in one way or another. It ... |
5-5-2017 at 15:19
by: Alice |
Why is glacial acetic acid needed in HOCl-oxidation of sec.OH?
I'd say the second mechanism is plausible as well. 
At least this is what happens when hypochlo ... |
5-5-2017 at 07:06
by: Alice |
Why is glacial acetic acid needed in HOCl-oxidation of sec.OH?
Sorry. 
Having a closer look at the mechanism, it seems unlikely the sec. alcohol is protonated ... |
5-5-2017 at 06:22
by: Alice |
Why is glacial acetic acid needed in HOCl-oxidation of sec.OH?
This is a "Beginnings" question.
Have a look at this video:
[url]https://www.youtube.com/watch ... |
5-5-2017 at 05:29
by: Alice |
Acetyl acetone as nucleophile
@Waffles. Your literature source displays a special case, which is achieved by generating disodioace ... |
30-4-2017 at 08:34
by: Alice |
Acetyl acetone as nucleophile
A bit more information would be nice. Is it your idea or somewhere from the literature? What solvent ... |
30-4-2017 at 00:30
by: Alice |
Experimental: Alternative to Al/Hg - the Al/Cu
Lordofthechemicals, your opinion about what should be legal and illegal doesn't matter if you're get ... |
29-4-2017 at 03:56
by: Alice |
Experimental: Alternative to Al/Hg - the Al/Cu
[quote]Copper isnt soluble in ether[/quote]
What do you mean by "copper"? I assume a copper salt? ... |
26-4-2017 at 04:24
by: Alice |
Aluminum alkoxide-amine adducts
Mini-workup is the standard procedure for TLCing TLC incompatible mixtures. If you can't separate th ... |
26-4-2017 at 03:39
by: Alice |
Experimental: Alternative to Al/Hg - the Al/Cu
Sometimes a solution looks almost colorless despite having some colored compounds in it which become ... |
22-4-2017 at 16:30
by: Alice |
Formic Acid Decomposition
@Boffis, from the paper I've cited before:
[quote]ALTHOUGH
the interaction of glycerol and oxali ... |
21-4-2017 at 07:37
by: Alice |
Formic Acid Decomposition
[url=http://pubs.rsc.org/en/content/articlelanding/1914/ct/ct9140500151]Interaction of Glycerol and ... |
20-4-2017 at 08:25
by: Alice |
Attempted synthesis of propyl 4 aminobenzoate
@diggafromdover, working with flames and ether is a really bad idea considering the extreme flammabi ... |
19-4-2017 at 07:34
by: Alice |
Report on Decarboxylation of Tryptophan in various solvents
@clearly_not_atara, why do you think it plays a role if the ketone is enolizable? The biocatalytic e ... |
17-4-2017 at 13:49
by: Alice |
Sulphur dioxide from sulphuric acid
Sulfur dioxide can be generated by treatment of sodium sulfite or sodium bisulfite with sulfuric aci ... |
17-4-2017 at 07:03
by: Alice |
Synthesis of longer chain tertiary alcohols
In the meantime I had two new ideas about obtaining long chain tertiary alcohols.
My first idea w ... |
17-4-2017 at 05:30
by: Alice |
Experimental: Alternative to Al/Hg - the Al/Cu
First of all, that's a very puzzling observation, alking.
So it turns red suddenly or constantly ... |
17-4-2017 at 04:02
by: Alice |
Molecular sieves - care and feeding
KOH is much more hygroscopic than magnesium sulfate, thus the following equilibrium is shifted more ... |
13-9-2016 at 05:10
by: Alice |
Molecular sieves - care and feeding
[quote]The paper also recommends KOH to dry ethanol, which is attractive due to its low cost (in the ... |
12-9-2016 at 04:39
by: Alice |
Drying ether for Grignard
Is calcium oxide suitable for drying ether? I didn't find any reference for it, but I can't find a r ... |
6-9-2016 at 01:09
by: Alice |
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