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Fire & Explosion risk vs. scale
[rquote=503394&tid=79679&author=Metacelsus][rquote=503392&tid=79679&author=AJKOER]
...
11-1-2018 at 07:38
by: AJKOER
Fire & Explosion risk vs. scale
My personal viewing of a childhood friend into chemistry that created and detonated some 5 ml of NCl ...
11-1-2018 at 05:43
by: AJKOER
Can butane melt silver?
Reduction in heating time can translate into success or failure if you are unsure of feasibility and ...
7-1-2018 at 12:47
by: AJKOER
Can butane melt silver?
My experience with a stove's methane flame is that perturbing the flame (by moving the lid slightly ...
7-1-2018 at 12:25
by: AJKOER
StaticShock2018's science fiction gadget, wishful thinking thermodynamics and arcane mental practices questions
On thermal reservoirs, think short term, like 24 hours. In places like Arizona with hot solar days a ...
4-1-2018 at 10:34
by: AJKOER
Most Efficient Way of Making HCl?
I find this to be one of the coolest path, but not orthodox that may result in an unexpected strong ...
4-1-2018 at 07:05
by: AJKOER
Kinetics and Mechanism of Oxidation of Hydroxylamine by Fe(lll)
Found a short paper, "Reaction pathways of hydroxylamine decomposition in the presence of acid/base" ...
4-1-2018 at 05:48
by: AJKOER
Kinetics and Mechanism of Oxidation of Hydroxylamine by Fe(lll)
A 2002 work “The kinetics and mechanism of oxidation of hydroxylamine by iron(III)” at http://pu ...
3-1-2018 at 13:19
by: AJKOER
Diclhloromethane synthesis
[rquote=497985&tid=78041&author=dan.vlad]"Direct conversion of Methane to Methanol, Chlorome ...
24-12-2017 at 17:36
by: AJKOER
Salts of Methyl Nitrite
Apparently, this source notes the use of flameless explosives in coal mines, see https://www.cdc.gov ...
15-12-2017 at 00:14
by: AJKOER
Salts of Methyl Nitrite
[rquote=500202&tid=78873&author=Sigmatropic]Really AJKOER? "detonation in situ"? It seems li ...
12-12-2017 at 19:10
by: AJKOER
Salts of Methyl Nitrite
Like with aqueous ammonia (an inorganic base) creating NH4NO2.

The latter is both very toxic and ...
12-12-2017 at 04:36
by: AJKOER
Birch reduction without ammonia
Unionised:

Look again, I now have two cited paths to the ethyl radical :o .

Note, the first pa ...
11-12-2017 at 15:41
by: AJKOER
Birch reduction without ammonia
[rquote=499770&tid=78790&author=clearly_not_atara]A common modification uses diethyl ether w ...
11-12-2017 at 09:21
by: AJKOER
Nitric Acid and Silver Nitrate
I was probably confused by my NaHSO4.H2O, which does exist! See http://www.endmemo.com/chem/compound ...
10-12-2017 at 12:58
by: AJKOER
Nitric Acid and Silver Nitrate
No need for any acid to make dilute HNO3 with a few easy steps from cheap available chemicals.

Fi ...
10-12-2017 at 07:38
by: AJKOER
Rocket Fuel from UV Photolysis of Alcohol/Aqueous Nitrate?
Melgar:

You may be right on the lack of need for a photo catalysis here as the burning of even a ...
8-12-2017 at 17:08
by: AJKOER
Fuming HNO3 distillation plan - suggestions?
Actually, no need to make or store dangerous 'super' strength nitric acid for nitrating purposes as ...
8-12-2017 at 07:04
by: AJKOER
TetraChloroMethane Using Carbon and Chlorine ?
[rquote=498758&tid=78554&author=PirateDocBrown]No. Chlorine is nowhere near as powerful an o ...
7-12-2017 at 07:33
by: AJKOER
TetraChloroMethane Using Carbon and Chlorine ?
[rquote=498756&tid=78554&author=unionised]It's possible, but you need to get it very hot
ht ...
6-12-2017 at 20:54
by: AJKOER
Long term experiment: does this make chlorosulfonic acid?
Per unionised comments, how water can act as a catalyst in the presence of light induced radicals, s ...
5-12-2017 at 14:56
by: AJKOER
Preparation of Thionyl Chloride
DJF90:

If we believe Wikipedia on SCl4 (link: https://en.wikipedia.org/wiki/Sulfur_tetrachloride ...
4-12-2017 at 13:08
by: AJKOER
Preparation of Thionyl Chloride
Here is an interesting chemically simple (but not likely simple in execution) direct path from atomi ...
4-12-2017 at 00:38
by: AJKOER
On the usefulness of amateur chemistry to society
Those with the knowledge of chemistry should be thankful for the currently limited and generally ine ...
3-12-2017 at 14:03
by: AJKOER
Preparation of S2Cl2
Per Atomistry.com on S2Cl2 (link: http://sulphur.atomistry.com/sulphur_monochloride.html), to quote: ...
2-12-2017 at 19:10
by: AJKOER
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