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What makes for example THF and MEK so much more powerful plastic solvents than acetone etc?
I mean basically solubility is a competition between the intermolecular cohesion forces of the solve ...
22-9-2021 at 05:37
by: clearly_not_atara
Thionyl chloride via the oxidation of SCl2 with a chlorate?
[rquote=665289&tid=157933&author=woelen]Pyrosulfate is not oxidizing and in-situ formation o ...
15-9-2021 at 12:33
by: clearly_not_atara
Thionyl chloride via the oxidation of SCl2 with a chlorate?
The difficulty of producing SOCl2 by the oxidation of SCl2 has to do with finding an oxidizer that i ...
15-9-2021 at 05:58
by: clearly_not_atara
Hydrazine
Found this while looking up something unrelated:
https://pubs.acs.org/doi/abs/10.1021/ja01063a013
...
10-9-2021 at 08:49
by: clearly_not_atara
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
It's plausible that AcCl and CS2 are both produced in this rxn, but I imagine that a lot of volatile ...
10-9-2021 at 07:35
by: clearly_not_atara
How toxic are Beryllium compounds really ?
The reason beryllium is feared is not that it is especially toxic. The reason is that [b]there is no ...
9-9-2021 at 14:15
by: clearly_not_atara
Future of carbon-free aviation ?
Elemental hydrogen in NH3 or CHx fuel fires might be present at a fraction of a percent of the parti ...
3-9-2021 at 14:38
by: clearly_not_atara
Using calcium chloride to remove MeOH from EtOH - Is it possible?
I doubt that separating MeOH from EtOH is easier than decarboxylating lactic acid. Apparently this c ...
3-9-2021 at 11:43
by: clearly_not_atara
Future of carbon-free aviation ?
I feel like you're overselling the space problem and underselling the chemistry problem with hydroge ...
2-9-2021 at 06:37
by: clearly_not_atara
Aluminum a rare earth metal ?
To me, conceptually, Al seems to fit in with In/Ga because their halides are Lewis acids, while scan ...
29-8-2021 at 15:00
by: clearly_not_atara
Can anything reasonably be done to improve Strontium Aluminate phosphorescense?
Sorry you got burned, but the short answer is that purifying this stuff is the worst, because the ma ...
21-8-2021 at 19:28
by: clearly_not_atara
Sulphuric acid from copper sulphate and sulphur dioxide???
Note that if you're considering sulfuric acid yield (HoPIC wasn't), the end of the equation should r ...
12-8-2021 at 07:47
by: clearly_not_atara
Any uses for lithium metal
Lithium can form radical anions with some polyaromatic compounds, such as naphthalene, biphenyl, etc ...
7-8-2021 at 11:10
by: clearly_not_atara
Oxalyl Chloride Challenge
Unfortunately atrazine is nowhere near as reactive as cyanuric chloride due to the electron density ...
5-8-2021 at 17:30
by: clearly_not_atara
Replacing halogen by hydrogen
[rquote=663414&tid=157763&author=unionised][rquote=663413&tid=157763&author=Texium] ...
31-7-2021 at 19:03
by: clearly_not_atara
Reaction of sulfur and TCCA
At least one SM member observed an [b][color=#880000]explosion[/color][/b] after attempting to disti ...
28-7-2021 at 16:29
by: clearly_not_atara
Electrophilic chlorination
I'm not convinced that aldimino/ketimino groups are ortho/para directing (or that they're compatible ...
21-7-2021 at 06:30
by: clearly_not_atara
Protecting groups for tertiary amines
[rquote=662990&tid=157678&author=njl]I think the phenolate will react much more quickly comp ...
21-7-2021 at 06:12
by: clearly_not_atara
Electrophilic chlorination
Snap back to reality: [i]why[/i] are you doing this? Why control the amount of Cl2 introduced into t ...
20-7-2021 at 16:15
by: clearly_not_atara
1,2 Dichloroethane
The major advantage of DCE over DCM is generally its higher boiling point. Very often when a paper c ...
15-7-2021 at 11:21
by: clearly_not_atara
Making alcohol solutions of hydrazine.
^bubble CO2? AFAIK hydrazinium carbonates are not stable and will decomp to the freebase.
3-7-2021 at 06:17
by: clearly_not_atara
stainless steel into sodium chromate through copper chromate
The monohydrogen phosphate <> dihydrogen phosphate pKa is 7.2 but the dichromate <> chro ...
2-7-2021 at 08:26
by: clearly_not_atara
How to get Hydrobromic acid (HBr) from Br2
You should consider that bromine is about fifty times as toxic as sulfur dioxide before attempting a ...
21-6-2021 at 21:01
by: clearly_not_atara
Carbon disulfide synthesis (alternative routes)
[quote]I don't think any metal can survive being red hot in a sulfur atmosphere...[/quote]
What if ...
17-6-2021 at 15:43
by: clearly_not_atara
Vicinal dione monoxime in aqueous medium?
I don't think HNO2 is blue... or likely to dissolve in butanone. More likely, you had N2O3 form and ...
17-6-2021 at 15:38
by: clearly_not_atara
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