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Is there a way to dissolve silver without HNO3?
I posted a thread about silver lactate earlier, which has roughly seven times the solubility of silv ...
19-1-2017 at 17:39
by: clearly_not_atara
re-use NO2 and Cl2
If your anhydride-forming equation is formally O2NOH + HCl >> H2O + O2NCl then the anhydride y ...
19-1-2017 at 17:21
by: clearly_not_atara
Get Your U.S. DBDMH While You Can!
What's the point of this? CBDMH is decidedly inferior for hot tubs (any chlorine is bad in a hot tub ...
30-12-2016 at 21:02
by: clearly_not_atara
Graphene oxidation using ferrate instead of permanganate and acid
Excuse me, I mis-posted; it's the ignition of KNO3 with [i]Fe[/i], not Fe2O3. Although it strikes me ...
28-12-2016 at 15:17
by: clearly_not_atara
Graphene oxidation using ferrate instead of permanganate and acid
Potassium ferrate is simply highly unstable. It can explode when concentrated, but usually it decomp ...
28-12-2016 at 05:01
by: clearly_not_atara
Our Entire Maths System is Fundamentally Wrong
Remember that mathematical truths are not facts in the sense of chemistry; rather, any set of mathem ...
25-12-2016 at 06:31
by: clearly_not_atara
re-use NO2 and Cl2
NO2 dissolves in water in the presence of oxygen to become nitric acid, although the reaction is slo ...
25-12-2016 at 00:07
by: clearly_not_atara
synthesis of methyl chloride with phosphorus trichloride
I'm sort of concerned that in the chlorination of a methane flame in air it is possible that some CO ...
21-12-2016 at 18:44
by: clearly_not_atara
Deep Eutectic Solvents, safe organolithium and fast alkylation
Perhaps the behavior can be explained by considering the sterics of the solvent-solvate complex. If ...
19-12-2016 at 10:57
by: clearly_not_atara
Benzotriazole and derivatives
I'm pretty sure step 5 is wrong; it produces 3-nitro-4-dimethylaminoacetanilide. Consider instead pe ...
5-12-2016 at 13:58
by: clearly_not_atara
MnO2 -> MnSO4; What is the best route?
I know this sounds utterly silly, but why not just try:

MnO2 + SO2 >> MnSO4

SO2 is a muc ...
2-12-2016 at 13:09
by: clearly_not_atara
Long term experiment: does this make chlorosulfonic acid?
I still with there was a way to move HSO4- ions into the SO2Cl2 phase. I have no idea what would qua ...
18-11-2016 at 14:16
by: clearly_not_atara
Acetaldehyde synthesis
Found this by accident, no really:

https://books.google.com/books?id=Cbc2AAAAQBAJ&pg=PT1830&a ...
17-11-2016 at 13:40
by: clearly_not_atara
Small fire while using BBr3
BBr3 reacts very enthusiastically with any source of hydroxyl groups. It probably heated up the meth ...
16-11-2016 at 17:38
by: clearly_not_atara
MITSUNOBU REACTION WITH PRIMARY AMIDES
The Mitsunobu reaction depends on the triphenylphosphine/diazo complex deprotonating the target nucl ...
16-11-2016 at 17:28
by: clearly_not_atara
Mercury-free Clemmensen reduction?
Not quite the same thing but:

https://erowid.org/archive/rhodium/chemistry/zn-ni.couple.html
12-11-2016 at 17:42
by: clearly_not_atara
Magnesium hydride
The preparation of magnesium hydride that we found in the OTC borohydride threads stated that the pr ...
3-11-2016 at 10:05
by: clearly_not_atara
chlorination of disodium pyro-H-phosphonate?
Phosphorous acid, H3PO3, is a misnomer; the molecule is diprotic HP(OH)2O, H-phosphonic acid, formin ...
31-10-2016 at 16:15
by: clearly_not_atara
Long term experiment: does this make chlorosulfonic acid?
I feel like you should have some kind of phase-transfer catalyst in that ampoule... it seems likely ...
29-10-2016 at 13:08
by: clearly_not_atara
Dry HBr gas
Use toluenesulfonic acid. If you have concentrated H2SO4, and you are trying to dissolve something i ...
28-10-2016 at 18:28
by: clearly_not_atara
Synthesis of Allylbenzene
On the one hand, it seems possible that some other reductants like dithionite (which IIRC does well ...
25-10-2016 at 17:57
by: clearly_not_atara
Synthesis of Allylbenzene
The arylzinc/allyl acetate method still seems attractive to me, even though acetonitrile is used as ...
22-10-2016 at 19:58
by: clearly_not_atara
Ammoniacal Silversulfamate Solution, Dangerous?
[quote]H2N- + OH- ⎯?→ H2O + HN(2-)
HN(2-) + OH- ⎯?→ H2O + N(3-)[/quote]

The pKa of NH3 - ...
22-10-2016 at 15:38
by: clearly_not_atara
Collection of colored gases/vapors
Oh -- you might be able to make trifluoronitromethane by the reactiin of chloropicrin with silver fl ...
17-10-2016 at 21:44
by: clearly_not_atara
Collection of colored gases/vapors
[quote=woelen] Making [nitrosotrifluoromethane] most likely is beyond the reach of nearly all amateu ...
17-10-2016 at 15:14
by: clearly_not_atara
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