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What makes for example THF and MEK so much more powerful plastic solvents than acetone etc?
I mean basically solubility is a competition between the intermolecular cohesion forces of the solve ... |
22-9-2021 at 05:37
by: clearly_not_atara |
Thionyl chloride via the oxidation of SCl2 with a chlorate?
[rquote=665289&tid=157933&author=woelen]Pyrosulfate is not oxidizing and in-situ formation o ... |
15-9-2021 at 12:33
by: clearly_not_atara |
Thionyl chloride via the oxidation of SCl2 with a chlorate?
The difficulty of producing SOCl2 by the oxidation of SCl2 has to do with finding an oxidizer that i ... |
15-9-2021 at 05:58
by: clearly_not_atara |
Hydrazine
Found this while looking up something unrelated:
https://pubs.acs.org/doi/abs/10.1021/ja01063a013
... |
10-9-2021 at 08:49
by: clearly_not_atara |
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
It's plausible that AcCl and CS2 are both produced in this rxn, but I imagine that a lot of volatile ... |
10-9-2021 at 07:35
by: clearly_not_atara |
How toxic are Beryllium compounds really ?
The reason beryllium is feared is not that it is especially toxic. The reason is that [b]there is no ... |
9-9-2021 at 14:15
by: clearly_not_atara |
Future of carbon-free aviation ?
Elemental hydrogen in NH3 or CHx fuel fires might be present at a fraction of a percent of the parti ... |
3-9-2021 at 14:38
by: clearly_not_atara |
Using calcium chloride to remove MeOH from EtOH - Is it possible?
I doubt that separating MeOH from EtOH is easier than decarboxylating lactic acid. Apparently this c ... |
3-9-2021 at 11:43
by: clearly_not_atara |
Future of carbon-free aviation ?
I feel like you're overselling the space problem and underselling the chemistry problem with hydroge ... |
2-9-2021 at 06:37
by: clearly_not_atara |
Aluminum a rare earth metal ?
To me, conceptually, Al seems to fit in with In/Ga because their halides are Lewis acids, while scan ... |
29-8-2021 at 15:00
by: clearly_not_atara |
Can anything reasonably be done to improve Strontium Aluminate phosphorescense?
Sorry you got burned, but the short answer is that purifying this stuff is the worst, because the ma ... |
21-8-2021 at 19:28
by: clearly_not_atara |
Sulphuric acid from copper sulphate and sulphur dioxide???
Note that if you're considering sulfuric acid yield (HoPIC wasn't), the end of the equation should r ... |
12-8-2021 at 07:47
by: clearly_not_atara |
Any uses for lithium metal
Lithium can form radical anions with some polyaromatic compounds, such as naphthalene, biphenyl, etc ... |
7-8-2021 at 11:10
by: clearly_not_atara |
Oxalyl Chloride Challenge
Unfortunately atrazine is nowhere near as reactive as cyanuric chloride due to the electron density ... |
5-8-2021 at 17:30
by: clearly_not_atara |
Replacing halogen by hydrogen
[rquote=663414&tid=157763&author=unionised][rquote=663413&tid=157763&author=Texium] ... |
31-7-2021 at 19:03
by: clearly_not_atara |
Reaction of sulfur and TCCA
At least one SM member observed an [b][color=#880000]explosion[/color][/b] after attempting to disti ... |
28-7-2021 at 16:29
by: clearly_not_atara |
Electrophilic chlorination
I'm not convinced that aldimino/ketimino groups are ortho/para directing (or that they're compatible ... |
21-7-2021 at 06:30
by: clearly_not_atara |
Protecting groups for tertiary amines
[rquote=662990&tid=157678&author=njl]I think the phenolate will react much more quickly comp ... |
21-7-2021 at 06:12
by: clearly_not_atara |
Electrophilic chlorination
Snap back to reality: [i]why[/i] are you doing this? Why control the amount of Cl2 introduced into t ... |
20-7-2021 at 16:15
by: clearly_not_atara |
1,2 Dichloroethane
The major advantage of DCE over DCM is generally its higher boiling point. Very often when a paper c ... |
15-7-2021 at 11:21
by: clearly_not_atara |
Making alcohol solutions of hydrazine.
^bubble CO2? AFAIK hydrazinium carbonates are not stable and will decomp to the freebase. |
3-7-2021 at 06:17
by: clearly_not_atara |
stainless steel into sodium chromate through copper chromate
The monohydrogen phosphate <> dihydrogen phosphate pKa is 7.2 but the dichromate <> chro ... |
2-7-2021 at 08:26
by: clearly_not_atara |
How to get Hydrobromic acid (HBr) from Br2
You should consider that bromine is about fifty times as toxic as sulfur dioxide before attempting a ... |
21-6-2021 at 21:01
by: clearly_not_atara |
Carbon disulfide synthesis (alternative routes)
[quote]I don't think any metal can survive being red hot in a sulfur atmosphere...[/quote]
What if ... |
17-6-2021 at 15:43
by: clearly_not_atara |
Vicinal dione monoxime in aqueous medium?
I don't think HNO2 is blue... or likely to dissolve in butanone. More likely, you had N2O3 form and ... |
17-6-2021 at 15:38
by: clearly_not_atara |
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