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Drying Acetic Acid?
Could you just add some sulfuric acid to the wet acetic acid before distilling to retain the water? ...
8-12-2021 at 06:38
by: garphield
Thionyl chloride via the oxidation of SCl2 with a chlorate?
The wikipedia article for POCl3 said that it can be prepared via the following reaction:

3 PCl3 + ...
14-9-2021 at 22:42
by: garphield
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
https://link.springer.com/article/10.1007/s42452-021-04777-0

Apparently acetate esters undergo th ...
14-9-2021 at 22:12
by: garphield
Oxalyl Chloride Challenge
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.5b01707

If this works for diacetyl, you'd be able to ...
13-9-2021 at 12:09
by: garphield
Glassware stuck together by sulfur from sulfur monochloride
[rquote=665165&tid=157917&author=unionised]Can you just melt the sulphur?[/rquote]

I trie ...
11-9-2021 at 11:54
by: garphield
Glassware stuck together by sulfur from sulfur monochloride
This happened like a month ago and I will be at uni until December but I may as well ask now since I ...
10-9-2021 at 11:44
by: garphield
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
Another potential idea would be to use MEK instead of acetone. Looking at the reaction mechanism in ...
10-9-2021 at 10:57
by: garphield
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
I was reading [url=https://pubs.acs.org/doi/pdf/10.1021/acs.joc.5b01707]a paper[/url] and came acros ...
9-9-2021 at 22:51
by: garphield
Reaction of sulfur and TCCA
Note: I am going to use sulfur chlorides to refer to SCl2 and/or S2Cl2, since both are interchangeab ...
25-7-2021 at 19:15
by: garphield
Tin orange iodine / chlorine compound with stable color
Was this an aqueous solution of HCl or was it dissolved in something else? If it was the former, thi ...
7-6-2021 at 18:47
by: garphield
Carbon disulfide synthesis (alternative routes)
The products of the reaction between calcium cyanamide and sulfur might be higher in sulfur and ther ...
7-6-2021 at 18:38
by: garphield
Help add to the sciencemadness wiki
For the page on ethylenediamine, can someone put the method RustyShackleford (think that was his use ...
31-5-2021 at 19:06
by: garphield
Carbon disulfide synthesis (alternative routes)
Cyanamide will react with hydrogen sulfide to generate thiourea (which will thermally decompose to g ...
30-5-2021 at 21:38
by: garphield
Can you still get an editor account on the wiki?
I would also like an account for the wiki, there are a few pages I think I could add to.
30-5-2021 at 18:33
by: garphield
Buying calcium cyanamide in the USA?
Apparently calcium cyanamide is pretty commonly used as a fertilizer, and there are several people s ...
30-5-2021 at 18:24
by: garphield
Carbon disulfide synthesis (alternative routes)
Maybe. Another option might be the reaction between cyanamide and SxCl2, which might be better since ...
17-5-2021 at 20:43
by: garphield
Carbon disulfide synthesis (alternative routes)
[url=http://sulphur.atomistry.com/perthiocyanogen.html]Perthiocyanogen[/url] decomposes on relativel ...
17-5-2021 at 18:46
by: garphield
DDNP & related compounds: The ├╝ber thread!
Picramic acid can act as a base, i.e. with isopicramic sulfate forming when picramic acid is combine ...
12-4-2021 at 07:59
by: garphield
Oleum using HPO3 as a dehydrating agent
[rquote=649253&tid=156549&author=Maurice VD 37]Why do you think the solution of metaphosphor ...
16-11-2020 at 15:56
by: garphield
Oleum using HPO3 as a dehydrating agent
I read Magpie's procedure for dehydrating orthophosphoric acid (H3PO4) to metaphosphoric acid (HPO3) ...
16-11-2020 at 12:23
by: garphield
Acid Chlorides
isn't there a thread on here somewhere where someone converted sodium acetate to acetyl chloride usi ...
9-10-2020 at 20:13
by: garphield
Aluminium metal + base as a dehydrating agent?
the reason i asked is because i am working on a synthesis of ethylenediamine from cheap materials an ...
9-10-2020 at 19:58
by: garphield
Aluminium metal + base as a dehydrating agent?
Wiki says reaction is NaOH + Al + 3 H2O -> NaAl(OH)4 + 3/2 H2. As this converts water into hydrox ...
26-9-2020 at 21:24
by: garphield
Most toxic compound OTC?
in terms of what has the lowest ld50 definitely americium from smoke detectors, however each one wil ...
17-9-2020 at 12:17
by: garphield
Chromate/Dichromate thermite
I did this using sodium chromate and 1/3rd of the weight of the chromate+aluminium of CaF2 as flux. ...
16-9-2020 at 09:16
by: garphield
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