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Mechanism of cathode corrosion in H3PO4/H2SO4?
Well, on dilution you get this reaction:

H2S2O8 + H2O = H2SO4 + H2SO5

If you somehow reduce H2 ...
2-3-2026 at 02:44
by: teodor
Separation of VO(2+) and Fe(2+/3+)
I think peroxide is not ideal oxidiser here because of presence of transition metals catalizing the ...
1-3-2026 at 11:01
by: teodor
Mechanism of cathode corrosion in H3PO4/H2SO4?
Hm, I never heard about getting oleum by H2SO4 electrolysis.
But the topic of H2SO4 electrolysis to ...
28-2-2026 at 08:33
by: teodor
Easy sulfite ion in a pinch...
[rquote=705833&tid=161412&author=semiconductive]
You can see a patent of mine used in nearl ...
28-2-2026 at 04:32
by: teodor
Easy sulfite ion in a pinch...
I didn't check the math, but in my opinion presence of an error doesn't make the work worthless. Som ...
27-2-2026 at 01:09
by: teodor
Easy sulfite ion in a pinch...
May be it can be useful, because those shadow libraries often change their domains, the up-to-day ac ...
26-2-2026 at 03:59
by: teodor
Easy sulfite ion in a pinch...
Of course you know that you can download almost any article for free or at a very small monthly paym ...
26-2-2026 at 01:37
by: teodor
Easy sulfite ion in a pinch...
[rquote=705802&tid=161412&author=semiconductive]
Aren't the equilibrium constants for the t ...
25-2-2026 at 14:37
by: teodor
Easy sulfite ion in a pinch...
[rquote=705746&tid=161412&author=semiconductive]
Equilibrium equations (2) and (3), talk ab ...
24-2-2026 at 01:05
by: teodor
Easy sulfite ion in a pinch...
[rquote=705746&tid=161412&author=semiconductive]Hmmm...
When I look up pka₁ of citric aci ...
23-2-2026 at 02:05
by: teodor
H2O2 By Electrolysis
This is a chapter from Gmelin Handbook about H2O2 distillation from Peroxydisulfuric Acid or its sal ...
22-2-2026 at 03:19
by: teodor
Easy sulfite ion in a pinch...
Hm, I think the solution is some salt of a transitional method with lower valency, like Cu(I), V(II) ...
19-2-2026 at 15:03
by: teodor
H2O2 By Electrolysis
[rquote=705736&tid=2150&author=Mister Double U]Hello teodor,

Do you by any chance have a ...
19-2-2026 at 13:46
by: teodor
H2O2 By Electrolysis
I have a book which compares different methods of producing H2O2 from persulfuric acid, ammonium and ...
17-2-2026 at 14:54
by: teodor
Easy sulfite ion in a pinch...
I’ve attached a chapter from Seidel / Linke book, it is about SO2 solubility in different substanc ...
16-2-2026 at 15:53
by: teodor
Disinfection of rainwater
Rainwater has some conductance due to adsorbing water from sea/lakes etc which is present in atmosph ...
13-2-2026 at 07:40
by: teodor
Weird Microwave Plasma from KNO3
You said your KNO3 was not dry. It can explain heating. To check wether it is the case try to repeat ...
13-2-2026 at 06:55
by: teodor
Easy sulfite ion in a pinch...
About your initial question of getting "free" (SO3)2- ion.
If we would skip a gass phase reactions ...
13-2-2026 at 03:23
by: teodor
Trouble with anhydrous cobalt and ferric sulfates
Look the chapter 2 of Basolo & Pearson, it describes the existing theories of coordination bond ...
13-2-2026 at 01:15
by: teodor
Trouble with anhydrous cobalt and ferric sulfates
I believe N is slightly more electronegative than Cl, according to Pauling’s study in 1932, but I ...
12-2-2026 at 14:22
by: teodor
Trouble with anhydrous cobalt and ferric sulfates
I promise to check those publications later, I don't have enough time now for that. Still I think I ...
11-2-2026 at 02:56
by: teodor
Z Library seized
Yes, this is how it is. The part of accumulated knowledge is in a hardly accessible form. Not everyt ...
11-2-2026 at 01:59
by: teodor
Free Offline Databases for Chemists: Organic Synthesis
Interesting. Did you include ChemInform abstracts also? I think this is one of most comprehensive so ...
10-2-2026 at 15:00
by: teodor
Favorite beginner experiments
Photographic printing. Black and white, toned, color processes. Inventing my own process.
Making bl ...
10-2-2026 at 13:14
by: teodor
Z Library seized
Zlib is an extention of the library genesis. The full copy of library genesis is 82 Tb, but not ever ...
10-2-2026 at 08:45
by: teodor
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