RIPPER - 25-9-2004 at 03:28
Are Caros Acid (H2SO4 + H2O2) a good oxidizer for a amino group ?
When the starting material dissolved in concentrated H2SO4
an than added the H2O2.
I have idea to make high percent H2O2, when the
normal H2O2 dissolved in acetic anhydride and than
added dropvise to the mix ?
BromicAcid - 25-9-2004 at 16:04
Yes, Caros acid is a good oxidizer for the amino group, as a matter of fact it can be used for the conversion of pentanitroanaline to
hexanitrobenzene.
unionised - 26-9-2004 at 14:43
Reaction of H2O2 and acetic anhydride can give peracetic acid, which is nasty and acetyl peroxide which is worse.
Adding this to sulphuric acid and an organic reducing agent isn't a reaction I would want to do.
Tacho - 27-9-2004 at 05:05
Isn't H2SO4+H2O2 known as "piranha solution" for its ability to chew away organics? Including flesh?
Hermes_Trismegistus - 27-9-2004 at 10:54
the frightener
high nitrated
RIPPER - 28-9-2004 at 04:15
Are high nitrated nitro anillines (phenols, anisols) not instable and high water soluble ?
anilline
RIPPER - 30-9-2004 at 04:58
I believe Trinitroaniline is a real makeable
energetic material.
PainKilla - 2-10-2004 at 17:00
Just made "pirahna acid" and it rightfully deserves that name! I mixed excess h2so4 with 30% h2o2, and palced a small amoutn (like 5 ml) on
this 1/8th thick opeice of cardboard...stuff ate right through it like 5 seconds. Everything began to smoke and smell of SOx im guessing... cool
stuff. I'd be careful with it though as I don't want to what it'd do the the flesh.... It's a claerish liquid with a pinkish tint
maybe.