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Pure vanillin from vanillin sugar
Can I extract vanillin from vanillin sugar? The only ingredients are vanillin and sugar.
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bahamuth
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You can, but wouldn't it be kinda expensive?
Use as dry ethanol as possible, sucrose is not very soluble in it; vanillin will dissolve nicely by the ethanol, filter and evaporate. (and
crystallize from water if greater purity is needed)
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Well, it's expensive, but how to get it except by that? How much yield could I get with that?
Thanks for this option of extraction 
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bahamuth
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I guess that the vanilla sugar contains somewhere from 1-5% vanilin/ethyl vanillin, and you should be able to get most of it out of the sugar, but why
not just buy it on ebay?
http://cgi.ebay.com/VANILLIN-100gm-Chemical-Methoxy-Hydroxy-...
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The problem is that I can't buy from ebay in my country so I will have to do it with ethanol. Is there alternative route with vanilla flavoring that
you can buy in shops?
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bahamuth
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How much if the stuff do you need, 5, 10g, or in the hundreds of grams?
Depending on your needs there is also a fairly easy way to prepare it from isoeugenol or eugenol, even from sawdust but the yields are apparently very
low.
"The Preparation of Vanillin from Eugenol and Sawdust", in: Journal of Chemical Education 1977, 54 (12), S. 776–778."
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I need just a few grams to make zingerone from vanillin and acetone. I should also look for clove oil to get eugenol.
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bahamuth
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Not to derail this thread but also made some zingerone a while back.., had a hell to separate it, oxidized in air and polymerized (or something) in
UV/florescent lighting.
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not_important
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If you have Middle Eastern/North African dry goods stores around you, you may find they stock bottles of pure vanillin.
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I wil then try to make that unsaturated ketone that is used to make zingerone.
Could I separate vanillin from sugar by dissolving all sugar in water (solubility: 2000g/L) and vanillin will be left out of solution. I would loose
1g of vanillin per 100ml of water.
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bahamuth
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Read up on the solubility of your compounds if you are trying to separate them by crystallization. Vanillin is very soluble in water so dissolving
your vanillin/sugar mixture in water will not work. As I said before, use ethanol, or even better when I think about it, ethylacetate or similar
esters.
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