Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: H2PtCl6 decomposition
zeolite2008
Harmless
*




Posts: 8
Registered: 14-11-2007
Member Is Offline

Mood: No Mood

[*] posted on 15-11-2007 at 20:57
H2PtCl6 decomposition


A paper says H2PtCl6 will decompose if heated, but no details.
I wonder at what temperature H2PtCl6 will decompose? and what is the decomposed product? I guess Pt, HCl, Cl2?
View user's profile View All Posts By User
12AX7
Post Harlot
*****




Posts: 4803
Registered: 8-3-2005
Location: oscillating
Member Is Offline

Mood: informative

[*] posted on 15-11-2007 at 22:25


Brauer (see our library) gives the preparation of PtCl4 from H2PtCl6, stating "the temperature must not be allowed to rise above 360°C". Since it must be dried in a stream of hot Cl2 gas, it's reasonable to assume it will decompose beyond 300°C or so into a mixture of platinum oxides, chlorides, and perhaps some metal as well.

Tim




Seven Transistor Labs LLC http://seventransistorlabs.com/
Electronic Design, from Concept to Layout.
Need engineering assistance? Drop me a message!
View user's profile Visit user's homepage View All Posts By User This user has MSN Messenger
Fleaker
International Hazard
*****




Posts: 1252
Registered: 19-6-2005
Member Is Offline

Mood: nucleophilic

[*] posted on 16-11-2007 at 09:35


It usually decomposes into a lower chloride. It will not decompose into its oxide Tim, not with Pt. It will actually go to metal first. I have a post coming soon that should address all of these Pd and Pt questions people seem to be having here, with gratuitous color photos!



Neither flask nor beaker.


"Kid, you don't even know just what you don't know. "
--The Dark Lord Sauron
View user's profile View All Posts By User

  Go To Top