amrhamed2
Hazard to Self
Posts: 60
Registered: 14-12-2007
Member Is Offline
Mood: No Mood
|
|
orthanilic acid
I have tried to make this acid via the procedure mentioned in orgsyn and things were ok
http://orgsynth.org/orgsyn/orgsyn/prepContent.asp?prep=CV2P0...
I searched beilstein and found other methods but in german
I need help in their procedure plz
The orgsyn method is multistep procedure and depends on o-chloro nitrobenzene where the disulfide is obtained first and then oxidized and chlorinated
using nitric acid and chlorine then finally reduced using iron and acetic acid
The other methods depends as long as I know on rearrangement of phenylsulfamic acid in such a manner that yields ortho isomer and not the para isomer
(I would like to know the details of such reaction plz
[Edited on 31-10-2008 by amrhamed2]
Attachment: fulltext.pdf (196kB) This file has been downloaded 560 times
amr h mahmoud
|
|
amrhamed2
Hazard to Self
Posts: 60
Registered: 14-12-2007
Member Is Offline
Mood: No Mood
|
|
and here is the orgsyn original paper
Attachment: fulltext imppppppppppp.pdf (544kB) This file has been downloaded 560 times
amr h mahmoud
|
|