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Author: Subject: H2O2 oxidations with molybdate catalyst
alchemizt
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[*] posted on 1-12-2025 at 15:30
H2O2 oxidations with molybdate catalyst


What substrates can this combination cleanly oxidise? Will it oxidise isopropanol to acetone? And cinnamaldehyde to cinnamic acid? Can it cleanly oxidise acetaldehyde yo acetic acid?
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[*] posted on 1-12-2025 at 17:07


Ummm. Touchy subject.

Generally speaking, oxidations can be hard to control. If the agent has any real mojo at all, it might oxidize Cinnamaldehyde to benzoic acid. This reputedly can be a problem when oxidizing Cinnamaldehyde with perborate in glacial acidic acid. Oxidation of the C=C double bond may occur, followed by decarboxylation.



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