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Author: Subject: Alternative solvent for the delepine reaction.
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[*] posted on 26-12-2020 at 20:47
Alternative solvent for the delepine reaction.

I am trying to make an amine, starting from a bromide. I am trying to find a better solvent than chloroform, preferably one that is environmentally better than CHCl3. I heard that ethanol can be used in another and that it gives better yields. I was wondering if there was any other solvent that could be used, because I might have time to test a bunch of solvents for a process that I am trying to optimize.
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Antigua
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[*] posted on 27-12-2020 at 03:57


https://scihub.wikicn.top/https://pubs.acs.org/doi/abs/10.10...
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RustyShackleford
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[*] posted on 27-12-2020 at 04:28


I have tried ethanol and acetic acid, ethanol was better. Substrate was benzyl chloride.
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[*] posted on 27-12-2020 at 21:24


@Antigua thanks for that paper.
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