| Pages:
1
2 |
Rainwater
National Hazard
Posts: 800
Registered: 22-12-2021
Member Is Offline
Mood: indisposition to activity
|
|
They NaOH is an isolation step. As it helps react FexClx to oxides
If starting from pure metal, you should be able to go stright to the oxidizer.
Searching for a reference now. Its in one of these books
Edit: still searching, got at least 1 book for every unfinished project
[Edited on 28-3-2024 by Rainwater]
Not the book im looking for but should help
https://www.sciencemadness.org/talk/viewthread.php?tid=6896
[Edited on 28-3-2024 by Rainwater]
"You can't do that" - challenge accepted
|
|
|
Chemgineer
Hazard to Others
Posts: 174
Registered: 25-5-2021
Member Is Offline
|
|
This looks promising, i'm getting an almost luminance orange colour now.
|
|
|
fx-991ex
Hazard to Self
Posts: 67
Registered: 20-5-2023
Member Is Offline
|
|
Quote: Originally posted by Rainwater  | They NaOH is an isolation step. As it helps react FexClx to oxides
If starting from pure metal, you should be able to go stright to the oxidizer.
Searching for a reference now. Its in one of these books
Edit: still searching, got at least 1 book for every unfinished project
[Edited on 28-3-2024 by Rainwater]
Not the book im looking for but should help
https://www.sciencemadness.org/talk/viewthread.php?tid=6896
[Edited on 28-3-2024 by Rainwater] |
Thats what am thinking too, once you oxidize the Cr it will stay in sln while the remaining metal-iron hydroxide precipitate will be discarded with
filtering.
React SS/Cr with acid - filter keep filtrate - react with carbonate(or bicarbonate?) - filter and keep precipitate - oxidize - filter and keep
filtrate - acidify to dichromate - react with KCl and keep precipitate.
[Edited on 28-3-2024 by fx-991ex]
|
|
|
Rainwater
National Hazard
Posts: 800
Registered: 22-12-2021
Member Is Offline
Mood: indisposition to activity
|
|
ISBN 0130-39913-2
Catherine E. Housecroft Inorganic Chemistry 2nd Edition
Chapter 21. Pg 606
Explains the ph solubility and how to convert chromium to all sorts of perty colors.
This isnt the reference im looking for but its a good one. Betterworldbooks has a few copies right now for less than 5$
I know i have a waste treatment and recovery book that goes through the entire process of extracting every transition metal from anything (dirt,
biomatter, sewage and industrial streams).
"You can't do that" - challenge accepted
|
|
|
Chemgineer
Hazard to Others
Posts: 174
Registered: 25-5-2021
Member Is Offline
|
|
So I left this filtering through a coffee filter and some cotton wool while I went away for a week.
I got back and the coffee filter is now brown/black and the cotton wool falls apart. I guess I do indeed have a good oxidiser.
|
|
|
| Pages:
1
2 |
![[*]](images/xpblue/default_icon.gif){kind=icon}
