jpsmith123
National Hazard
Posts: 764
Registered: 24-6-2005
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"Sulphoxide Explosives"
Someone may find this interesting:
http://www.sciencemadness.org/talk/files.php?pid=262896&...
And here's the paper that referenced it:
http://www.sciencemadness.org/talk/files.php?pid=262872&...
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VladimirLem
Hazard to Others
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Mood: Have no fear <Vlad> is here.
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"Sorry, you are not permitted to view this forum"
meh
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jpsmith123
National Hazard
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Sorry aboout that...those links take you to the reference section (which requires special access).
I'll attach the patent and paper here.
Attachment: GB1129777A.pdf (321kB)
This file has been downloaded 522 times
Attachment: Journal_of_Chemical_Crystallography,_1998,_Volume_28,_Number_3,_Pages_213-216[1].pdf (210kB)
This file has been downloaded 517 times
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Hexavalent
International Hazard
Posts: 1564
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Location: Wales, UK
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Vladimir, ask Polverone for access.
"Success is going from failure to failure without loss of enthusiasm." Winston Churchill
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franklyn
International Hazard
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DMSO Handle With Care
http://dchas.org/phocadownload/JCHAS%20Archives/1994/1994-1-...
DMSO is Acetone with the central 2 position carbon replaced with Sulfur
which makes it more susceptable to oxidation. Even a lame oxidizer
such as TCCA will runaway. See section 10 here _
http://www.phy.duke.edu/research/chempatt/msds/MSDS_DMSO.pdf
Perchlorate salts mixed with any fuel is pyrotechnic , not only DMSO see also _
Bretherick’s Handbook of Reactive Chemical Hazards 6th ed.
Volume I - Dimethyl Sulfoxide ( page 336 ) see Metal Oxosalts page 339
Volume II - Solvated Oxosalt Incidents , on page 370
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PHILOU Zrealone
International Hazard
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About the GB patent,
I have serious doubts about the decomposition reaction pathways described...
To my feeling AlCl3 can't result from the reaction of Al(OClO3)3...
Simple electronegativity check will tell Al2O3 or Al(OH)3 must result (Al being the most electropositive and O the more electronegative) aside some
HCl and H2S also.
For the rest any molecular mix of an oxydiser and a reducer/fuel must be considered critical and powerful...in the event of a mishaps, spontaneous
decomposition...
PH Z (PHILOU Zrealone)
"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
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