morganism
Hazard to Others
Posts: 105
Registered: 8-12-2012
Location: Az.
Member Is Offline
Mood: No Mood
|
|
Iron as catalyst to amides
low tech route
http://www.sciencedaily.com/releases/2013/02/130203145436.ht...
|
|
|
chemrox
International Hazard
Posts: 2961
Registered: 18-1-2007
Location: UTM
Member Is Offline
Mood: LaGrangian
|
|
We may have a new expression in the making, "morganism." Definition: A morganism is a post with reference(s) but little or no other content leaving
one wondering, "was there a point?" I'm an advocate of Green Chemistry. The article seems to indicate some new ground breaking on the GC front. If
that was the point.... You might have discussed a possible application related to your interests. Or you could have suggested the use of FeSO4 etc.
in someone's recently reported experiment or posted question... I am in favor of a Green Chemistry sub-forum but there would have to be enough
interest and activity to ask P to set it up.
"When you let the dumbasses vote you end up with populism followed by autocracy and getting back is a bitch." Plato (sort of)
|
|
|
morganism
Hazard to Others
Posts: 105
Registered: 8-12-2012
Location: Az.
Member Is Offline
Mood: No Mood
|
|
I thought the new thread just above discussing converting to amides shows there was some interest in a simple and easy to aquire materials catalyst.
You physics teachers are tough !
If i come across some interesting chem techniques, i post it up here.
One liners seem to be most helpful to skimmers, associations i leave to the experts here...
|
|
|
Rich_Insane
Hazard to Others
Posts: 371
Registered: 24-4-2009
Location: Portland, Oregon
Member Is Offline
Mood: alive
|
|
Is there a journal reference in there somewhere?
Edit: Nevermind I found it.
"Subhash Chandra Ghosh, Joyce S. Y. Ngiam, Christina L. L. Chai, Abdul M. Seayad, Tuan Thanh Dang and Anqi Chen. Iron-catalyzed efficient synthesis of
amides from aldehydes and amine hydrochloride salts. Advanced Synthesis & Catalysis, Volume 354, Issue 8, May 21, 2012, Pages: 1407%u20131412 DOI:
10.1002/adsc.201200020"
I'd be wary though, I tried a similar method using copper sulfate to isomerize the oxime (formed in situ via one-pot reaction from the aldehyde) and
it was absolute crap.
Can anyone get the full paper though?
[Edited on 5-2-2013 by Rich_Insane]
[Edited on 5-2-2013 by Rich_Insane]
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
