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Carboxylic acid -> Alkan
I believe that it could work. But previously it would be necessary to attack with PI3 to make iodide ...
5-7-2007 at 16:19
by: Filemon
Carboxylic acid -> Alkan
Sorry but that it's an example the HI/P doesn't reduce carboxilic acid. Alone it reduces the group h ...
5-7-2007 at 16:14
by: Filemon
Carboxylic acid -> Alkan
[quote][i]Originally posted by garage chemist[/i]
EDIT: Page 301 in the Gattermann from 1909. Also ...
5-7-2007 at 02:13
by: Filemon
Clemmensen reduction
[quote][i]Originally posted by Filemon[/i]
Does it also reduce a halogen in alpha position?
[Edit ...
4-7-2007 at 15:09
by: Filemon
decomposition benzalacetone
Does somebody know that product produces the decomposition to the air and light of the benzalcetone? ...
4-7-2007 at 04:28
by: Filemon
Acetic anhydride preparation
[quote][i]Originally posted by garage chemist[/i]
Acetic anhydride from sodium acetate, using S2Cl2 ...
3-7-2007 at 11:39
by: Filemon
Clemmensen reduction
I have a doubt on the Clemmensen reduction with Zn-Hg/HCl. Does it also reduce a halogen in alpha po ...
1-7-2007 at 04:01
by: Filemon
nitrostyrene
How can one obtain the sodium salts of nitromethane (I mean to isolate them)?
29-6-2007 at 15:36
by: Filemon
nitrostyrene
I don't understand the synthesis proposed in Rhodium. For that so much cold? Would not it harm the d ...
28-6-2007 at 16:42
by: Filemon
alkylation of nitrocompounds
Thank you. I had looked for information on the reaction but I didn't find information. Then polyalky ...
18-6-2007 at 03:38
by: Filemon
alkylation of nitrocompounds
The reactions of alkylation of nitro compounds take place polyalkylation?

CH2-NO2- Na+ + ...
17-6-2007 at 16:54
by: Filemon
HNO3????
A better way to make nitrite is this way:

3Fe(OH)2 (s) + 2NO3 - (ac) => Fe3O4 (s) + 2N ...
14-6-2007 at 16:21
by: Filemon
Carboxylic acid -> Alkan
[quote][i]Originally posted by roamingnome[/i]
[quote]
Do you know this decarboxylation? I don't k ...
10-6-2007 at 16:03
by: Filemon
Carboxylic acid -> Alkan
Do you know this decarboxylation? I don't know their name.

R-COONa + NaOH + CaO + Heat => R-H ...
9-6-2007 at 16:48
by: Filemon
toluene --> benzaldehyde
[quote][i]Originally posted by S.C. Wack[/i]

benzyl bromide and sodium nitrate: [url=http://v3.es ...
3-6-2007 at 17:06
by: Filemon
Cinnamaldehyde as Insecticide/Fungicide
Can it become purified for crystallization? cinnamaldehyde mp -7.5, eugenol mp -9.2
27-5-2007 at 04:24
by: Filemon
Peroxide Safety
Would it also work FeCl3 to remove the peroxides?
24-5-2007 at 12:15
by: Filemon
Permanganates
[quote][i]Originally posted by woelen[/i]
Are you sure that it is not NaCl with some NaMnO4 mixed i ...
17-5-2007 at 15:39
by: Filemon
Permanganates
I have synthesized NaMnO4 with 2MnCl2 + 5NaClO (aprox.15%) + 6NaOH. The reaction is very quick. Surp ...
17-5-2007 at 04:17
by: Filemon
The lead salts preparation thread!
[quote][i]Originally posted by dann2[/i]
Hello,

Can PbO be made in a straight forward manner fr ...
11-5-2007 at 13:02
by: Filemon
toluene --> benzaldehyde
[quote][i]Originally posted by garage chemist[/i]
An advantage of bromine is that benzotribromide c ...
30-4-2007 at 16:02
by: Filemon
HNO3????
Yes it is possible:

http://en.wikipedia.org/wiki/Ammonium_nitrite

But it was probably oxid ...
29-4-2007 at 11:54
by: Filemon
HNO3????
[quote][i]Originally posted by Theoretic[/i]
An answer on the original question: H2O2 reacts with a ...
29-4-2007 at 11:20
by: Filemon
HNO3????
[quote][i]Originally posted by Theoretic[/i]
An answer on the original question: H2O2 reacts with a ...
28-4-2007 at 03:57
by: Filemon
toluene --> benzaldehyde
[quote][i]Originally posted by S.C. Wack[/i]
There are of course a jillion ways to do things...they ...
4-4-2007 at 16:59
by: Filemon
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