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Sodium nitrate/urea complex
Interesting find. The paper mentions that the complex looses water easily and then breaks down into ...
18-12-2009 at 16:21
by: Taoiseach
Sodium nitrate/urea complex
Excellent work franklyn !

Replacing the hydrate water with H2O2 sure looks very promising but mig ...
9-12-2009 at 04:05
by: Taoiseach
Synthetic route to tetrazoles from urea & ammonium nitrate
"5. Presence of ammonium chloride prevents joint precipitation of zinc salts then sodium hydrocarbon ...
7-12-2009 at 09:30
by: Taoiseach
Cr2O3 can be dissolved in water easily
The other idea I had was to make perchromic acid by adding H2O2 to a suspension of Cr(OH)3 and leavi ...
4-12-2009 at 08:09
by: Taoiseach
Cr2O3 can be dissolved in water easily
@woelen

CrO3 precipartes as extremely fine crystals from dichromate+H2SO4. Its extremely troubles ...
2-12-2009 at 00:57
by: Taoiseach
Cr2O3 can be dissolved in water easily
How about dissolving Cr2O3 in bromic acid obtained from H2SO4+Ba(BrO3)2? This should give CrO3 upon ...
1-12-2009 at 07:54
by: Taoiseach
Hydrazine
You dont need silver, copper will do fine.
1-12-2009 at 00:18
by: Taoiseach
Preparation of elemental phosphorus
The chemistry is all figured out already. Dozens of books out there (some available 4free @archive.o ...
20-11-2009 at 00:38
by: Taoiseach
Exotic Primaries - Complex Salts
Interesting... nice video thx.

I have never heard of any other stable complexes of this kind. You ...
12-11-2009 at 13:10
by: Taoiseach
Preparation of ionic nitrites
Some interesting tidbits from "Chemistry - inorganic and organic" by Charles Loudon Bloxam (1883 lol ...
12-11-2009 at 02:45
by: Taoiseach
Preparation of ionic nitrites
Some info on sodium hyponitrite.
31-10-2009 at 13:58
by: Taoiseach
Preparation of ionic nitrites
@Sedit

Zinc does indeed reduce nitrate in aequos solution but it won't stop at the nitrite unfort ...
31-10-2009 at 13:56
by: Taoiseach
Hydroquinone Synthesis
@S.C.Wack

Do you have a preparation of hydroquinone from p-benzoquinone at hand?
27-10-2009 at 03:50
by: Taoiseach
Synthetic route to tetrazoles from urea & ammonium nitrate
@497

There's several problems: Reducing 100g NQ would take over 40h at 5 amps. Higher currents a ...
26-10-2009 at 02:33
by: Taoiseach
Reagent Production by Electrolysis - a few ideas.
Some nice ideas there DerAlte!

I made several Cu(I) and Cu(II) salts by electrolysis. Generally s ...
15-10-2009 at 14:37
by: Taoiseach
Synthetic route to tetrazoles from urea & ammonium nitrate
What a pleasure to read. Simply awesome!

Great work engager & thx for your efforts.

Btw I ...
14-10-2009 at 22:58
by: Taoiseach
Ammonium acetate
Try acetone. It works well to precipate other acetates (tried on Ca, Pb, Ba, Na) which are generally ...
6-10-2009 at 23:07
by: Taoiseach
Preparation of cyanides
Ammonium cyanide from K4FeCN6 and NH4Cl is confirmed by "the chemistry of cyanogen compounds" p. 39, ...
4-10-2009 at 05:11
by: Taoiseach
Free hypochlorous acid in aqueous solution
I once made a pretty conc. solution of HOCl in an attempt to make chlorates from just sodium carbona ...
1-10-2009 at 03:31
by: Taoiseach
Exotic Primaries - Complex Salts
@Formatik

thx for the interesting upload. From which book are these excerpts?

I feel some misg ...
30-9-2009 at 22:48
by: Taoiseach
Preparation of cyanides
[rquote=163335&tid=23&author=garage chemist]Ullmanns Encyclopedia says 0,57g/100g in 100% Et ...
29-9-2009 at 22:50
by: Taoiseach
Preparation of cyanides
Anyone has reliable figures on KCN's solubility in hot ethanol?

All I could find is a vague remar ...
29-9-2009 at 08:29
by: Taoiseach
Preparation of cyanides
Reduction of cyanate with C yields cyanide contaminated with carbonate. The books says that pure KCN ...
28-9-2009 at 07:42
by: Taoiseach
Preparation of cyanides
The preparation from ferrocyanide+salmiac is also mentioned on wikipedia:

http://en.wikipedia.org ...
27-9-2009 at 08:10
by: Taoiseach
Preparation of cyanides
Its a German book and available online:

http://www.archive.org/details/dieindustrieder00khgoog

...
27-9-2009 at 07:14
by: Taoiseach
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