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Japanese nuclear reactor problems
[quote]But, as with any engineering project, you have to draw a line somewhere otherwise nothing wou ...
16-3-2011 at 17:23
by: madscientist
Reactions
You need to learn the material, not just ask others to do your homework for you. That's called [i]ch ...
16-3-2011 at 07:32
by: madscientist
Japanese nuclear reactor problems
ScienceHideout: when fuel rods are exposed, they begin to melt. When they are completely molten, it' ...
15-3-2011 at 15:34
by: madscientist
Japanese nuclear reactor problems
I think they're more concerned about a decrease in surface area at this point. Anything that joins t ...
15-3-2011 at 14:12
by: madscientist
Japanese nuclear reactor problems
And although as time goes on, the material becomes less fissile, the surface area decreases as the r ...
15-3-2011 at 11:35
by: madscientist
Japanese nuclear reactor problems
"Don't worry, the situation is under control," they said. Kaboom. "Oh, not much radiation leaking," ...
14-3-2011 at 17:01
by: madscientist
DMF substitute in Wacker oxidation?
Are you sure about this? A google search revealed that dimethylfumurate has been banned by the EU, b ...
10-3-2011 at 07:22
by: madscientist
DMF substitute in Wacker oxidation?
It should work. Even protic solvents such as t-BuOH have been used. But I would read a review paper ...
9-3-2011 at 10:12
by: madscientist
How to stabilize freshly prepared H2O2?
Phosphoric acid is a common stabilizer. But be careful your source is clean. It's frequently contami ...
7-3-2011 at 13:00
by: madscientist
Keeping OTC chemicals OTC and bringing back home chemistry
[quote]not so much synthesize, more like possess and preserve. I can concentrate and preserve and as ...
7-3-2011 at 07:27
by: madscientist
Trimethylsulfonium bromide and its use for the methylation of phenols
Great work Nicodem! It's nice to know we can methylate phenols in an amateur environment without dea ...
6-3-2011 at 11:46
by: madscientist
New Energetic Materials - Current Research
[i]Where are your references?[/i] Your source doesn't cite a single one!
2-3-2011 at 18:53
by: madscientist
Hydrazine
[quote]I believe he was banned last time for spewing inane procedures that he had pulled out of his ...
2-3-2011 at 18:51
by: madscientist
Security of reagent orders from chemical companies in this age of chemophobia, paranoia and the oppressive health and safety nan
[quote].I've taught classes of kids older than you.[/quote]

And plenty who taught your generation ...
28-2-2011 at 23:09
by: madscientist
Iso-Butyl Nitrite
Back on topic, please!
25-2-2011 at 23:26
by: madscientist
Protecting phenols in a grignard reaction
Benzyl ethers can be cleaved in other ways too - strong acids, oxidation to benzoate and removal wit ...
23-2-2011 at 15:53
by: madscientist
Preparation of elemental phosphorus
Perhaps I'm overlooking something obvious, but it seems the use of SiO<sub>2</sub> with ...
18-2-2011 at 11:27
by: madscientist
Amateur chemist set off explosion near my home
The Energetic Materials section is not going anywhere.

There may be no real point in making PETN. ...
16-2-2011 at 13:17
by: madscientist
priming mixture for loading percussion caps
Every other post in this thread mentions firearms. Weapons discussion is forbidden on Sciencemadness ...
16-2-2011 at 10:56
by: madscientist
Amateur chemist set off explosion near my home
The Energetics Materials section does have a lot of problem posts. Please use the "Report" button on ...
16-2-2011 at 10:38
by: madscientist
Strong acids
garage_chemist, here's an excerpt from the Sixth Edition of Cotton's Advanced Inorganic Chemistry (p ...
15-2-2011 at 17:06
by: madscientist
L-tryptophan decarboxylation
Esters react with amines to form amides - I would use a different solvent.
15-2-2011 at 09:22
by: madscientist
LED Dangers - Unbelievable Paranoia!
Attention: anyone who wants to argue about atmospheric sciences should take it elsewhere.
13-2-2011 at 11:46
by: madscientist
Hofmann degradation and Amide hydrolysis
Crap - I meant to say "With hydrolysis of amides..." Sorry! :D
12-2-2011 at 13:35
by: madscientist
Hofmann degradation and Amide hydrolysis
With amides, deprotonation doesn't yield a reaction, hence it's unimportant. With the Hofmann rearra ...
12-2-2011 at 12:27
by: madscientist
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