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Concentrating hydrobromic acid higher than the azeotrope?
As I recall, HBr/GAA can catalyze some reactions where conc H2SO4 would give oxidation products. It' ...
16-10-2021 at 16:00
by: clearly_not_atara
Concentrating hydrobromic acid higher than the azeotrope?
https://www.osti.gov/etdeweb/biblio/8148785

HBr likely displays typical zeotropy with the boiling ...
14-10-2021 at 20:09
by: clearly_not_atara
CBD as a chemotherapy agent (split from CBD solubility in organic solvents)
[rquote=666140&tid=158004&author=Tsjerk]That are some impressive doses :) what is that? 1000 ...
14-10-2021 at 19:51
by: clearly_not_atara
How is an electrolyte different from a conductor?
In a [i]metallic[/i] conductor, electrons form a Fermi gas, a quantum mechanical phenomenon with no ...
11-10-2021 at 14:42
by: clearly_not_atara
Preparation of NaH from sodium metal.
In the case of ethyllithium its thermal decomposition to the hydride is indeed discussed in the lite ...
5-10-2021 at 08:24
by: clearly_not_atara
Oxidation of SO2 to SO3 in pyrosulfuryl chloride
On further consideration, you might consider chlorine dioxide, which is a liquid below 11 C.

[Edit ...
1-10-2021 at 20:14
by: clearly_not_atara
Oxidation of SO2 to SO3 in pyrosulfuryl chloride
The reaction of SO2 with Cl2 produces sulfuryl chloride, which is basically just a liquid chlorinati ...
1-10-2021 at 07:26
by: clearly_not_atara
Oxidation of SO2 to SO3 in pyrosulfuryl chloride
Where are you planning to get pyrosulfuryl chloride, is my first question...?

Anyway, since we ar ...
1-10-2021 at 06:56
by: clearly_not_atara
Calcium Sulphate Destroys Glassware
If you want to do a dry distillation, you can probably protect your glassware by using a eutectic mi ...
30-9-2021 at 16:13
by: clearly_not_atara
What makes for example THF and MEK so much more powerful plastic solvents than acetone etc?
I mean basically solubility is a competition between the intermolecular cohesion forces of the solve ...
22-9-2021 at 05:37
by: clearly_not_atara
Thionyl chloride via the oxidation of SCl2 with a chlorate?
[rquote=665289&tid=157933&author=woelen]Pyrosulfate is not oxidizing and in-situ formation o ...
15-9-2021 at 12:33
by: clearly_not_atara
Thionyl chloride via the oxidation of SCl2 with a chlorate?
The difficulty of producing SOCl2 by the oxidation of SCl2 has to do with finding an oxidizer that i ...
15-9-2021 at 05:58
by: clearly_not_atara
Hydrazine
Found this while looking up something unrelated:
https://pubs.acs.org/doi/abs/10.1021/ja01063a013
...
10-9-2021 at 08:49
by: clearly_not_atara
Production of carbon disulfide + acyl chlorides via the reaction of sulfur monochloride with methyl ketones
It's plausible that AcCl and CS2 are both produced in this rxn, but I imagine that a lot of volatile ...
10-9-2021 at 07:35
by: clearly_not_atara
How toxic are Beryllium compounds really ?
The reason beryllium is feared is not that it is especially toxic. The reason is that [b]there is no ...
9-9-2021 at 14:15
by: clearly_not_atara
Future of carbon-free aviation ?
Elemental hydrogen in NH3 or CHx fuel fires might be present at a fraction of a percent of the parti ...
3-9-2021 at 14:38
by: clearly_not_atara
Using calcium chloride to remove MeOH from EtOH - Is it possible?
I doubt that separating MeOH from EtOH is easier than decarboxylating lactic acid. Apparently this c ...
3-9-2021 at 11:43
by: clearly_not_atara
Future of carbon-free aviation ?
I feel like you're overselling the space problem and underselling the chemistry problem with hydroge ...
2-9-2021 at 06:37
by: clearly_not_atara
Aluminum a rare earth metal ?
To me, conceptually, Al seems to fit in with In/Ga because their halides are Lewis acids, while scan ...
29-8-2021 at 15:00
by: clearly_not_atara
Can anything reasonably be done to improve Strontium Aluminate phosphorescense?
Sorry you got burned, but the short answer is that purifying this stuff is the worst, because the ma ...
21-8-2021 at 19:28
by: clearly_not_atara
Sulphuric acid from copper sulphate and sulphur dioxide???
Note that if you're considering sulfuric acid yield (HoPIC wasn't), the end of the equation should r ...
12-8-2021 at 07:47
by: clearly_not_atara
Any uses for lithium metal
Lithium can form radical anions with some polyaromatic compounds, such as naphthalene, biphenyl, etc ...
7-8-2021 at 11:10
by: clearly_not_atara
Oxalyl Chloride Challenge
Unfortunately atrazine is nowhere near as reactive as cyanuric chloride due to the electron density ...
5-8-2021 at 17:30
by: clearly_not_atara
Replacing halogen by hydrogen
[rquote=663414&tid=157763&author=unionised][rquote=663413&tid=157763&author=Texium] ...
31-7-2021 at 19:03
by: clearly_not_atara
Reaction of sulfur and TCCA
At least one SM member observed an [b][color=#880000]explosion[/color][/b] after attempting to disti ...
28-7-2021 at 16:29
by: clearly_not_atara
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