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Protecting groups for tertiary amines
[rquote=663094&tid=157678&author=Monoamine][rquote=662526&tid=157678&author=karlosĀ³ ...
21-7-2021 at 05:11
by: njl
Protecting groups for tertiary amines
I think the phenolate will react much more quickly compared to the amine.
17-7-2021 at 07:02
by: njl
Protecting groups for tertiary amines
Or deprotonate and perform William ether synthesis
17-7-2021 at 06:32
by: njl
Means of titrating calcium cyanamide
I think measuring the amount of ammonia given off during hydrolysis is your best bet. Hydrolyze a kn ...
4-7-2021 at 05:31
by: njl
Preparation of NaH from sodium metal.
No, elimination of a beta hydrogen + electron from an alkoxide would give a carbonyl and hydride, el ...
30-6-2021 at 12:55
by: njl
Preparation of NaH from sodium metal.
Might the same concept apply to more easily obtained alkoxides? Equivalent beta elimination would gi ...
30-6-2021 at 04:49
by: njl
foaming Borax!
Maybe forming NaHCO3 and boric acid?
28-6-2021 at 02:35
by: njl
How do reactions at electrodes proceed: Peroxidation vs. Esterification vs. unknown synthesis.
The answers to many of these questions may be found in the chemistry of radicals. Reading up on radi ...
25-6-2021 at 16:59
by: njl
Chemicals & Glassware for Sale - Price Drop
HAD to snatch up that NaBH4 and NaBF4. Arrived as 2 bottles of NaBF4 and some bags of NaBH4. The ind ...
25-6-2021 at 16:35
by: njl
Thionly chloride from batteries
I've looked into it a little, they seem very expensive for a frankly tiny amount of SOCl2
25-6-2021 at 16:27
by: njl
Preparation of NaH from sodium metal.
I was more familiar with sodium hydride's deprotonation of the 3 position on indoles. What is it str ...
24-6-2021 at 13:09
by: njl
Is there anything interesting I can do with Urea?
[rquote=661835&tid=157609&author=S.C. Wack]
Indirectly, urea has been used to decarboxylate ...
20-6-2021 at 08:29
by: njl
What does "drying over" some desiccant mean?
It is also (perhaps incorrectly) used to mean drying a product in a sealed vessel containing the dry ...
19-6-2021 at 17:08
by: njl
Is diphosphorus pentoxide hygroscopic?
Yeah
19-6-2021 at 06:39
by: njl
Latest chemical order?
This is probably not the right place for it but I thought I'd mention I saw moth killer at the hardw ...
17-6-2021 at 06:44
by: njl
Uses of NaClO?
Aqueous phosgene...
15-6-2021 at 10:41
by: njl
16 oz of nitroethane. Buy or nah?
At least we know now. I suppose that also applies to [url=https://www.universalcompanies.com/product ...
13-6-2021 at 05:30
by: njl
Proposed novel 6-step syntheis of 5-MeO-4-AcO-DMT
Needs references
13-6-2021 at 05:25
by: njl
Oxalyl Chloride Challenge
What if we tried chlorinating glyoxal???
9-6-2021 at 08:10
by: njl
Choice of oxidants for tinder

[quote]
KBrO3 - 69 g/l @ 20 C, 167 g/mol, 0,41 mol/l
KClO3 - 81 g/l @ 25 C, 122 g/mol, 0,66 mol/ ...
7-6-2021 at 12:49
by: njl
16 oz of nitroethane. Buy or nah?
[quote]
I always get back just a little bit more product than the amount of aldehyde I put in
[/qu ...
7-6-2021 at 12:45
by: njl
The Short Questions Thread (4)
Carboxylic acids can be activated by formation of mixed anhydrides. Could the acid instead be reacte ...
6-6-2021 at 16:12
by: njl
Preparation of dimethyl carbonate without autoclave or phosgene
As you know ethylene glycol is less volatile than methanol so beyond using a large excess of methano ...
5-6-2021 at 10:17
by: njl
Indole-3-Carbinol Oxidation
I think we all have a few "side projects" like that collecting dust :D
5-6-2021 at 06:29
by: njl
Indole-3-Carbinol Oxidation
To what end, karl? Just out of curiosity.
5-6-2021 at 05:54
by: njl
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