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Author: Subject: How to make diphenyl sulfide?
jonco
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[*] posted on 23-11-2010 at 15:50
How to make diphenyl sulfide?

Does anyone know how to make diphenyl sulfide using readily available chemicals? Or where to obtain it?

Thanks
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Ozone
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[*] posted on 23-11-2010 at 17:48


Check this out, it looks like it might provide some insight for you:

http://www.sciencemadness.org/talk/viewthread.php?tid=13406

I found this using the search engine on the upper left-hand side of the page.

Another route can be found here:

http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv2...

Cheers,

O3



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[*] posted on 24-11-2010 at 03:50


The first method will not work to make diphenyl sulphide as it relies on the nitro group to activate the ring to nucleophilic attack.
Plain old chlorobenzene will just sit there and smile at you!
The second method will work for diphenyl sulphide.
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Ozone
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[*] posted on 24-11-2010 at 05:41


The point was to demonstrate the search engine.



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madscientist
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24-11-2010 at 07:14
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[*] posted on 24-11-2010 at 07:24


Quote: Originally posted by Ozone  
The point was to demonstrate the search engine.


Fair enough.
I thought that I would point out that the first reaction is not generally applicable but is a group of special cases.
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[*] posted on 24-11-2010 at 09:39


Fair enough :)



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