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Author: Subject: Black Flame?!
Bert
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[*] posted on 23-2-2023 at 09:30
Black Flame?!


A visual effect produced by illuminating a table salt doped alcohol flame which produces the typical orange-y sodium spectrum with a monochrome sodium spectrum electric light. See attached images, check out the linked short video.

https://youtube.com/shorts/uUGzrS5tpLc?feature=share

Now. Where can I get strontium, barium, boron and potassium spectrum lamps- Or other suitably tunable light sources.

And how did I avoid hearing about this effect before?

20230223_111054.jpg - 351kB




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Cathoderay
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[*] posted on 23-2-2023 at 14:27


It seems Physicists and Chemists do not talk with each other very much.
That is a good demonstration of Absorption Spectroscopy.
https://en.wikipedia.org/wiki/Absorption_spectroscopy
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Sulaiman
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[*] posted on 23-2-2023 at 19:24


Quote: Originally posted by Bert  


Now. Where can I get strontium, barium, boron and potassium spectrum lamps- Or other suitably tunable light sources.


I think that a low cost option is a broad spectrum lamp (tungsten halogen, HID etc), lenses and/or mirrors, a diffraction grating and a couple of adjustable slits.
And a lot of miscellaneous materials and work.
A spectroscope in reverse.
I'd expect very low light levels, and a not truly monochromatic light spectrum, but may be zdoable.

If as a hobby project then I'd consider making the narrow bandwidth light source easily reversible to be a spectroscope?
And later as a spectrometer?
I'd consider it, but probably never do it :(

Other than a few industrial applications, and very specific educational purposes,
I guess that spectral lamps would be high cost per use in an amateur setting.

[Edited on 24-2-2023 by Sulaiman]




CAUTION : Hobby Chemist, not Professional or even Amateur
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[*] posted on 23-2-2023 at 20:35


I bookmarked much the same thing a year or so ago intending to show the video to a class. Have not had the opportunity yet.
https://www.youtube.com/watch?v=F0LWtieip9E

I note that there are quite a few videos on this. Most of them shorts.




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[*] posted on 24-2-2023 at 04:24


Mercury vapor behaves similarly with the UV light from a mercury arc lamp but you need a fluorescent screen to see the effect.

abs-Hg- vap-Capture.JPG - 19kB

See: https://www.youtube.com/watch?v=TZprgqZh4IE




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Bert
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[*] posted on 24-2-2023 at 06:52


The only tunable monochrome light source I've ever worked with would be a bit... Expensive.



aladdin-electron.jpg - 143kB




Rapopart’s Rules for critical commentary:

1. Attempt to re-express your target’s position so clearly, vividly and fairly that your target says: “Thanks, I wish I’d thought of putting it that way.”
2. List any points of agreement (especially if they are not matters of general or widespread agreement).
3. Mention anything you have learned from your target.
4. Only then are you permitted to say so much as a word of rebuttal or criticism.

Anatol Rapoport was a Russian-born American mathematical psychologist (1911-2007).

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