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Author: Subject: DTBE
majdo
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[*] posted on 22-2-2006 at 07:18
DTBE


You may find many ways of preparation of almost every ether.However I haven't found anything about di-t-buthyl ether synthesis.I searched also in ACS or Elseviere publications.

The only path I have found out was synthesis of di-t-buthyl peroxide (from t-buthanol) then treat it with 1 equivalent of triphenylphosphine (found in old book about phosphorus compounds).
I don't know if this has any practical use,since I would be afraid to deal with peroxides :)
Does anyone know a better way?




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[*] posted on 22-2-2006 at 10:24


Correct spelling makes a big difference:
di-t-BUTYL ether




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[*] posted on 22-2-2006 at 13:49


Oh you are right,but I DID search "butyl".I wrote "buthyl" because I confuse it with methyl and ethyl.In my language there is no "h" in any case :P



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S.C. Wack
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[*] posted on 22-2-2006 at 15:45


http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/1941/63/i06/...
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[*] posted on 23-2-2006 at 08:36


Thank You!



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