kclo4
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the stucture for splendidin
i have searched all over for its structure! and i am unable to find it anywhere or for that matter really anything about it other then its effects and
that it is a neo-clerodane diterpenoid similar to Salviarin
could someone please help me find its structure?
perhaps one of you guys have a book with it in it, or something?
I'm dieing to know its chemical structure 
not that i want to beg but please help
thank you
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Nicodem
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| Quote: | Originally posted by kclo4
i have searched all over for its structure! and i am unable to find it anywhere or for that matter really anything about it other then its effects and
that it is a neo-clerodane diterpenoid similar to Salviarin |
You have not been trying that very hard have you?
Elucidation of the structure of splendidin and salviarin from Salvia splendens:
Splendidin, a new trans-clerodane from Salvia splendens.
J. Chem. Soc., Perkin Trans. 1, (1979) 533 – 534.
Giuseppe Savona, Maria Pia Paternostro, Franco Piozzi and James R. Hanson
DOI: 10.1039/P19790000533
Salviarin, a new diterpenoid from Salvia splendens.
J. Chem. Soc., Perkin Trans. 1, (1978) 643 – 646.
Giuseppe Savona, Maria Pia Paternostro, Franco Piozzi, James R. Hanson, Peter B. Hitchcock and Sunday A. Thomas
DOI: 10.1039/P19780000643
Other structural studies of splendidin, salviarin and other diterpenes from Salvia splendens:
Complete 1H and 13C NMR assignments of clerodane diterpenoids of Salvia splendens.
Magn. Reson. Chem., 44, (2006) 962-965.
Fontana G, Savona G, Rodriguez B.
DOI: 10.1002/mrc.1869
Clerodane diterpenoids from Salvia splendens.
J. Nat. Prod., 69, (2006) 1734-1738.
Fontana G, Savona G, Rodriguez B.
DOI: 10.1021/np068036d
BONUS:
Elucidation of the structure of salvinorins A and B (also known as divinorins A and B) from from Salvia divinorum:
Salvinorin, a new trans-neoclerodane diterpene from Salvia divinorum(Labiatae).
J. Chem. Soc., Perkin Trans. 1, (1982) 2505 – 2508.
Alfredo Ortega, John F. Blount and Percy S. Manchand
DOI: 10.1039/P19820002505
Divinorin A, a psychotropic terpenoid, and divinorin B from the hallucinogenic Mexican mint, Salvia divinorum.
J. Org. Chem., 49, (1984) 4716 – 4720.
Leander J. Valdes, III William M. Butler, George M. Hatfield, Ara G. Paul, Masato Koreeda
DOI: 10.1021/jo00198a026
Elucidation of the structure of a clerodane diterpene from Salvia rubescens:
Labiaten-Bitterstoffe: Eine neue Verbindung des Clerodantyps.
Chemische Berichte, 106, (1973) 922 – 928.
Carl Heinz Brieskorn, Traugott Stehle
DOI: 10.1002/cber.19731060324
[Edited on by Nicodem]
…there is a human touch of the cultist “believer” in every theorist that he must struggle against as being
unworthy of the scientist. Some of the greatest men of science have publicly repudiated a theory which earlier they hotly defended. In this lies their
scientific temper, not in the scientific defense of the theory. - Weston La Barre (Ghost Dance, 1972)
Read the The ScienceMadness Guidelines!
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kclo4
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THANK YOU VERY MUCH! 
for all of the links and pictures
Ps. i am unable to buy/open or whatever with the PDF files, so if it has had its structure in them, i wouldn't be able to see them anyways
so thats likely the reason i couldn't find its stucture
[Edited on 18-3-2007 by kclo4]
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