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Author: Subject: making hard water soft for shaving purpose
edouard
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[*] posted on 5-12-2008 at 23:29
making hard water soft for shaving purpose


hi

i have a hard water and cannot built consistent lather.

what would be the easiest way to solve the problem without loosing time with filtration.

i mean what product sould i use considering i don't want to produce nasty byproducts for my face

thanks
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domaani
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[*] posted on 6-12-2008 at 00:42


I suggest getting a reverse osmosis apparatus.
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Picric-A
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[*] posted on 6-12-2008 at 02:44


cant you just buy a water softener?
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hissingnoise
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[*] posted on 6-12-2008 at 06:32


Or finally grow a beard, like the rest of us. . .
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12AX7
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[*] posted on 6-12-2008 at 08:00


Borax was always used in laundry for that, wasn't it?

Tim




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watson.fawkes
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[*] posted on 6-12-2008 at 08:45


Washing soda got its name by scavenging the metal ions that make water hard (principally calcium and magnesium), preventing them from binding to surfactant molecules. More recent practice is to use trisodium phosphate (TSP) to complex these ions. Both of these are available off the shelf in most areas. This being a significant consumer chemical category, there are a number of other agents and methods used, should you want to get experimental. This class of chemicals are called "builders" in the trade.

Borates, on the other hand, are in the class of bleaches.

The easiest way to use this is to mix up a wash bottle of "lather water" and squirt some in when it's time to shave. Do a few trials with increasing concentrations to find a mix that works for you.
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edouard
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[*] posted on 6-12-2008 at 23:48


thanks for your answers,

Quote:
Originally posted by watson.fawkes
Washing soda got its name by scavenging the metal ions that make water hard (principally calcium and magnesium),


considering that washing soda will increase pH of my basic hard water,

what pH can take my face?

thanks
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12AX7
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[*] posted on 7-12-2008 at 05:35


Quote:
Originally posted by edouard
what pH can take my face?


Oh, pH 10 and over will irritate and more than 12 will, quite literally, "take your face".

Tim




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watson.fawkes
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[*] posted on 7-12-2008 at 09:26


The pH of washing soda, dissolved in pure water, is 11. But you wouldn't be dissolving it in pure water, but in water that already has metal ions in it. Neither magnesium nor calcium carbonate is very soluble in water, so adding the first bit of washing soda will cause precipitation. The pH won't rise very much until this precipitation is finished.

In other words, don't start with a double fistful.
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edouard
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[*] posted on 8-12-2008 at 02:36


Quote:
Originally posted by watson.fawkes
The pH of washing soda, dissolved in pure water, is 11.


doing my homeworks i noted that baking sode (a less effective softener) acts as a buffer,

mixing them should prevent excessive pH increase, no?
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not_important
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[*] posted on 8-12-2008 at 04:35


It would, but then calcium and magnesium bicarbonates are somewhat soluble, indeed being the type of water hardness referred to as "'temporary hardness" because on boiling the CO2 is driven off and the normal carbonates precipitate out.
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edouard
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[*] posted on 8-12-2008 at 05:14


Quote:
Originally posted by not_important
It would, but then calcium and magnesium bicarbonates are somewhat soluble,


i understand that Ca & Mg bicarbonates will contribute to hardness as Ca2+ & Mg2+ did.

so what would make a better buffer in this situation? vinegar?

thanks
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watson.fawkes
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[*] posted on 8-12-2008 at 05:54


You only need a buffer if you're putting in too much base. So don't put in too much base. You can tell when you've got too much base with a pH indicator. Turmeric (the spice) is a pH indicator with a broad transition range, from yellow at 7.4 to orange/red at 8.5. You can use a titration test with indicator to tell you how much base to use when you mix up an ordinary batch.
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edouard
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[*] posted on 8-12-2008 at 07:00


thanks,

so considering hard water is definied as concentration > 100mg/l of CaCO3 equiv

i would say 0.5 g/l Na2CO3 would be a good start.
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watson.fawkes
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[*] posted on 8-12-2008 at 19:33


500 mg/L Na<sub>2</sub>CO<sub>3</sub> seems a reasonable starting point. Remember though, that at the end of the day, you're measuring the amount of Ca<sup>2+</sup> and Mg<sup>2+</sup> in your water. Some amount of experimentation is going to be necessary until you have an estimate of just how hard your water is.
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edouard
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[*] posted on 8-12-2008 at 20:43


Quote:
Originally posted by watson.fawkes
500 mg/L Na<sub>2</sub>CO<sub>3</sub> seems a reasonable starting point. Remember though, that at the end of the day, you're measuring the amount of Ca<sup>2+</sup> and Mg<sup>2+</sup> in your water. Some amount of experimentation is going to be necessary until you have an estimate of just how hard your water is.


thanks

so considering its solvability is 30g/L i make 2L bottle of distilled water with 50g in order to ease my "cooking"
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JohnWW
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[*] posted on 8-12-2008 at 21:03


What about passing it through a laboratory-type deionizer, which consists mainly of a column packed with ion-exchange resin beads?
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[*] posted on 9-12-2008 at 05:38


Borates, carbonates oh my! Lets stray from the harsh alkaline ream for a moment as not overlook a gentler alternative. ZEOLITES! The polyphosphates, metaphosphate, and orthophosphate builders of yesteryear have been subplanted with zeolite substitutes. At least where I live I can go to the pet store in the fish section, and buy "lab grade Zeolite" used for ammonia removal. I ran 25% NaCl solution through a column of this twice and all or most of the naturally occuring calcium was removed. Potassium chloride would work even better. So convert your zeolite into the sodium moeity, shake vigorously with a couple litres of your tap water and filter it out with your fresh decalcified water.



Fellow molecular manipulator
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Phosphor-ing
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[*] posted on 9-12-2008 at 06:22


Or you can just buy distilled(soft) water by the gallons, cheap.



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edouard
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[*] posted on 9-12-2008 at 06:51


Quote:
Originally posted by chloric1
I ran 25% NaCl solution through


you wrote 25% right i.e. 250g NaCl/L ????
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edouard
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[*] posted on 9-12-2008 at 06:52


Quote:
Originally posted by Phosphor-ing
Or you can just buy distilled(soft) water by the gallons, cheap.


well, the carbonate solution sounds even cheaper
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