Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
 Pages:  1  2
Author: Subject: synthesis of O-nitroaniline
nitro-genes
International Hazard
*****




Posts: 1029
Registered: 5-4-2005
Member Is Offline


[*] posted on 26-3-2018 at 16:09


Would the sulfonation/nitration also work for toluene? Adding toluene to a very large excess of 98% sulfuric, heat until homogenous. Add 1 to 1.1 mole eqvt of the strongest nitric possible. React at lowest temp possible that still allows nitration (15-40 C maybe?) for long timer (maybe up to several days). Add water (enough to dissolve sulfonic acids), filter off any DNT formed, heat under reflux, and collect relatively pure 2-nitro toluene? Or would a few % water in the sulfuric and the more activated unsulfonated toluene really still result in a mixture of isomers? Or would the temperature needed for the nitration be too high too not exclude ipso nitration enough?
View user's profile View All Posts By User
 Pages:  1  2

  Go To Top