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ManyInterests
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I got another cleaning question. I just read DennyDevHE77 post about compressing it in layers of newspaper (newsprint paper is available any art
supply store) if that is actually sufficient to purify the stuff without much more washing that would quite fascinating.
I was reviewing the synthesis videos and I did see at the end stage when they crash the nitration liquid in water they scoop away the crude TNT from
the liquid as it seems to float on the top. How is the rest of that liquid disposed of? Simply dilute, neutralize and flush away, or does it need to
be treated like it has some red water?
[Edited on 3-2-2024 by ManyInterests]
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OneEyedPyro
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Quote: Originally posted by ManyInterests  | I got another cleaning question. I just read DennyDevHE77 post about compressing it in layers of newspaper (newsprint paper is available any art
supply store) if that is actually sufficient to purify the stuff without much more washing that would quite fascinating.
I was reviewing the synthesis videos and I did see at the end stage when they crash the nitration liquid in water they scoop away the crude TNT from
the liquid as it seems to float on the top. How is the rest of that liquid disposed of? Simply dilute, neutralize and flush away, or does it need to
be treated like it has some red water?
[Edited on 3-2-2024 by ManyInterests] |
Are you referring to purifying crude TNT that has simply been crashed out of the nitration mix and filtered off? I doubt pressing it between paper is
going to do much except remove water, you'll still have an acidic product with some lower nitrate and unwanted side product contamination.
If we're trying to be environmentally friendly here then incineration or long term containment are your best options for any kind of TNT waste.
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ManyInterests
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| Quote: Originally posted by OneEyedPyro | | Quote: Originally posted by ManyInterests | I got another cleaning question. I just read DennyDevHE77 post about compressing it in layers of newspaper (newsprint paper is available any art
supply store) if that is actually sufficient to purify the stuff without much more washing that would quite fascinating.
I was reviewing the synthesis videos and I did see at the end stage when they crash the nitration liquid in water they scoop away the crude TNT from
the liquid as it seems to float on the top. How is the rest of that liquid disposed of? Simply dilute, neutralize and flush away, or does it need to
be treated like it has some red water?
[Edited on 3-2-2024 by ManyInterests] |
Are you referring to purifying crude TNT that has simply been crashed out of the nitration mix and filtered off? I doubt pressing it
between paper is going to do much except remove water, you'll still have an acidic product with some lower nitrate and unwanted side product
contamination.
If we're trying to be environmentally friendly here then incineration or long term containment are your best options for any kind of TNT waste.
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No I was referring to the left over water from that crash. The crude TNT I know I will need either to recrystalize in alcohol or to wash with sodium
bisulfite until no red water is produced.
The red water I am aware now how to get rid of... just evaporate it off and incinerate what is left behind. That isn't difficult. I many containers
and a blowtorch and I can find many places to do it easily.
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DennyDevHE77
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| Quote: Originally posted by OneEyedPyro | | Are you referring to purifying crude TNT that has simply been crashed out of the nitration mix and filtered off? I doubt pressing it between paper is
going to do much except remove water, you'll still have an acidic product |
What I meant is perfectly clear from my comment:
| Quote: Originally posted by DennyDevHE77 | | it can be compressed in layers of newspapers so that they absorb dinitro derivatives. You can add calcium silicate so that it absorbs TNT oil.
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I do not know where you saw here that I claimed that such an operation would allow you to get a product free of acids. I was talking about the
purification of TNT from dinitro derivatives, that is, from TNT oil. They make TNT weaker, oily, and can be released during storage. Although I think
even this is not particularly important for home use. And then, it will remove a significant amount of TNT oil, but not all of it.
And as for the acidic product, all aromatic explosives are generally acidic, and they are not afraid of acids. If you do not think in the future to
fuse them with nitroesters (which are alkaline by nature, and which are just afraid of acids), then I do not see the point in cleaning from acids.
Meanwhile, due to the acidic nature of TNT, the alloy of chemically pure TNT and PETN still leads to decomposition, increased acidity and increased
sensitivity after 3-4 years of storage.
[Edited on 4-2-2024 by DennyDevHE77]
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ManyInterests
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| Quote: |
I do not know where you saw here that I claimed that such an operation would allow you to get a product free of acids. I was talking about the
purification of TNT from dinitro derivatives, that is, from TNT oil. They make TNT weaker, oily, and can be released during storage. Although I think
even this is not particularly important for home use. And then, it will remove a significant amount of TNT oil, but not all of it.
And as for the acidic product, all aromatic explosives are generally acidic, and they are not afraid of acids. If you do not think in the future to
fuse them with nitroesters (which are alkaline by nature, and which are just afraid of acids), then I do not see the point in cleaning from acids.
Meanwhile, due to the acidic nature of TNT, the alloy of chemically pure TNT and PETN still leads to decomposition, increased acidity and increased
sensitivity after 3-4 years of storage.
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I understand. What I am asking is before purification, the water you use to crash out the crude TNT. Is that anything special or do I neutralize it
and pour it down the drain? the same way I neutralize and pour down the drain all the other water from other nitrations I do? (ETN, PETN, RDX, etc,).
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DennyDevHE77
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I wasn't answering you.
But regarding your question, nitromass with TNT is usually poured into water, the TNT is filtered out, and it is washed several times with water.
All other cleaning, if reasonable, is done after that.
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ManyInterests
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OK, so that water from initial washing is no different than any other nitration. Gotcha.
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OneEyedPyro
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It contains some amount of TNT, lower nitrates and side products, in my experience the crash water smells awfully strong of those contaminates.
Neutralization and dilution isn't going to remove it.
Dumping it down the drain is irresponsible, even if you're logically just one guy contributing a very tiny fraction of pollution compared to the rest
of the world.
Any TNT waste is best off being evaporated down and incinerated.
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ManyInterests
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| Quote: Originally posted by OneEyedPyro |
It contains some amount of TNT, lower nitrates and side products, in my experience the crash water smells awfully strong of those contaminates.
Neutralization and dilution isn't going to remove it.
Dumping it down the drain is irresponsible, even if you're logically just one guy contributing a very tiny fraction of pollution compared to the rest
of the world.
Any TNT waste is best off being evaporated down and incinerated. |
OK I understand. All water must be evaporated and incinerated.
I will need to put forward my intended plan once I have figured out exactly what I want to do. I've been doing some research and I want to find the
most economical and simplest way to do it. Ditto for cleaning it and properly disposing of all the unwanted byproducts. It almost reminds me of how I
was during my picric acid synths, being all fretting more over cleaning the product than the synthesis of the product itself.
If there is one thing I am worried about it is the leftover sulfuric acid. Since that is not something that can be evaporated and incinerated away. It
can be purified I guess, then I can reuse the acid?
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OneEyedPyro
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| Quote: Originally posted by ManyInterests | | Quote: Originally posted by OneEyedPyro |
It contains some amount of TNT, lower nitrates and side products, in my experience the crash water smells awfully strong of those contaminates.
Neutralization and dilution isn't going to remove it.
Dumping it down the drain is irresponsible, even if you're logically just one guy contributing a very tiny fraction of pollution compared to the rest
of the world.
Any TNT waste is best off being evaporated down and incinerated. |
OK I understand. All water must be evaporated and incinerated.
I will need to put forward my intended plan once I have figured out exactly what I want to do. I've been doing some research and I want to find the
most economical and simplest way to do it. Ditto for cleaning it and properly disposing of all the unwanted byproducts. It almost reminds me of how I
was during my picric acid synths, being all fretting more over cleaning the product than the synthesis of the product itself.
If there is one thing I am worried about it is the leftover sulfuric acid. Since that is not something that can be evaporated and incinerated away. It
can be purified I guess, then I can reuse the acid? |
Some gentle heating, a bit of air flow and time is how I've always done it. The larger the surface area of the liquid the faster it will go. Using
multiple evaporating dishes and leaving it in the sun, putting heating pads underneath etc helps.
Sulfuric acid is industrially recycled from nitration waste. I'm not sure how exactly but it likely involves filtration and distillation, I'd have to
assume that bringing sulfuric acid to those temps would turn anything left from the nitration into little more than tar.
I'm sure someone here has suggestions.
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Sir_Gawain
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Heating an acid mixture that possibly contains an explosive just seems like a bad idea to me. Even a few milligrams detonating can break your
apparatus and send hot sulfuric acid everywhere.
“Alchemy is trying to turn things yellow; chemistry is trying to avoid things turning yellow.” -Tom deP.
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DennyDevHE77
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In industry, acids do regenerate. They begin with "denitration", that is, nitrogenous derivatives, nitrogen oxides are extracted, then nitric acid is
separated from sulfuric acid, nitric acid is processed (into dilute, into ammonium nitrate) and sulfuric acid is concentrated and returned to the
cycle. This is the usual option.
Moreover, in industry, it is ensured that no more than 1% of nitro derivatives are present in the waste acid, and only in "mono" form. Moreover, the
monoform can pass into -di and -trinitroproducts in the process of denitration.
So first, the nitro mixture is diluted with water (to reduce the solubility of the nitro compounds), and the nitro mixture is defended, after which
the nitro products are separated. Then (sometimes) polyunitro compounds are extracted using solvents, as is done in the production of picric acid and
tetryl. Sometimes they are oxidized. Then the nitro mixture is diluted to 68-70%, this is necessary to remove nitrosylseric acid HNSO4. It is fragile
in itself, decomposes when heated, but it is very stable in sulfuric acid above 75%.
So they dilute it to 68-70% and heat it up, and everything volatile flies away from sulfuric acid. That is, nitrogen oxides and nitric acid. All this
is driven off through a denitration column.
The resulting dilute sulfuric acid is concentrated with flue gases 650-1000C
(obtained by burning fuel oil or methane).
At least that's how the industry goes) at home, you can just dilute the nitro mixture a little, defend, remove the nitro derivatives and surpass the
nitrogen mixture. But this is not possible with every nitro compound. For example, a nitro mixture after the synthesis of rdx is extremely thermally
unstable and cannot be distilled, and a nitro mixture after the synthesis of EGDN or nitroglycerin contains a lot of them, and it is defended for 8-10
days.
And about sewage. Don't do nonsense. Rinse the TNT on the filter a couple of times with water and rinse in the sink. Laboratories do exactly the same
thing. The mass of nitro derivatives that will go into the wastewater is so minimal that it is stupid to think about it, after all, you do not have a
plant with the synthesis of tens of thousands of tons.
[Edited on 8-2-2024 by DennyDevHE77]
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ManyInterests
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| Quote: Originally posted by DennyDevHE77 |
And about sewage. Don't do nonsense. Rinse the TNT on the filter a couple of times with water and rinse in the sink. Laboratories do exactly the same
thing. The mass of nitro derivatives that will go into the wastewater is so minimal that it is stupid to think about it, after all, you do not have a
plant with the synthesis of tens of thousands of tons.
[Edited on 8-2-2024 by DennyDevHE77] |
I always did think that. I guess the same with the red water? The bacteria in the sewer could also make short work for it like it does with hydrazine
waste.
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