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Author: Subject: Oxidation state and Charges
DraconicAcid
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[*] posted on 12-5-2014 at 08:31


Quote: Originally posted by woelen  
- Metals have positive oxidation states.


Usually. There are carbonyl complexes such as K2Fe(CO)4 in which the metal has a negative formal oxidation state. John Ellis, in Minnesota, did quite a bit of work on trying to make compounds with the most negative possible formal oxidation states on the metals (I almost did a post-doc with him, but took a different offer first).

http://pubs.acs.org/doi/abs/10.1021/ja00448a021?journalCode=... has Mn(CO)4-3, which has a metal in its -3 oxidation state (formally, at least, although much of the negative charge will actually be on the oxygens of the carbonyl ligands).

And then there are aurides, in which gold is int he -1 oxidation state:
http://www.fkf.mpg.de/134290/Aurides

[Edited on 12-5-2014 by DraconicAcid]




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