vulture
Forum Gatekeeper
Posts: 3330
Registered: 25-5-2002
Location: France
Member Is Offline
Mood: No Mood
|
|
Catalyzed nitration of aromatics
While browsing through my acros catalogue looking for zirconium compounds, I discovered something interesting.
The acros catalogue usually displays some applications for the chemicals they sell and this is what I found under zirconiumoxide, ZrO2:
ZrO2/sulfate-catalyzed nitration of aromatic compounds: Nagi SH.M. et al.; Khim., 7,1650-1652 (1990)
My question: does anyone now which journal Khim. is and where I could find it?
Also, did anybody hear about this procedure?
Zirconium compounds might be pricey, but alot of chinese and indian manufacturers will probably sell them for quite a competitive price without
questions asked, trust me...
One shouldn't accept or resort to the mutilation of science to appease the mentally impaired.
|
|
|
mitch77
Harmless
Posts: 3
Registered: 19-2-2003
Member Is Offline
Mood: No Mood
|
|
I think that ZnO2 is used catalytically in the vapor phase nitration of benzene and other aromatics. Halfnium looks popular in that arena too.
|
|
|
PHILOU Zrealone
International Hazard
Posts: 2893
Registered: 20-5-2002
Location: Brussel
Member Is Offline
Mood: Bis-diazo-dinitro-hydroquinonic
|
|
Many nitrates of transition metals are very strong nitrating agents (oxydising too).
Cerium teranitrate, Pb(NO3)4, Ti(NO3)4,...
They are used in aromatic nitration because they are so strong oxydisers that nitration in aliphatic serie produces only decomposition products!
I'll see if I find good examples!
PH Z (PHILOU Zrealone)
"Physic is all what never works; Chemistry is all what stinks and explodes!"-"Life that deadly disease, sexually transmitted."(W.Allen)
|
|
|
Dany
Hazard to Others
Posts: 482
Registered: 3-8-2013
Member Is Offline
Mood: No Mood
|
|
Quote: Originally posted by vulture  | While browsing through my acros catalogue looking for zirconium compounds, I discovered something interesting.
The acros catalogue usually displays some applications for the chemicals they sell and this is what I found under zirconiumoxide,
ZrO<sub>2</sub>:
ZrO<sub>2</sub>/sulfate-catalyzed nitration of aromatic compounds: Nagi SH.M. et al.; Khim., 7,1650-1652 (1990)
My question: does anyone now which journal Khim. is and where I could find it?
Also, did anybody hear about this procedure?
Zirconium compounds might be pricey, but alot of chinese and indian manufacturers will probably sell them for quite a competitive price without
questions asked, trust me...
|
vulture,
The reference for the nitration using ZrO2/sulfate is:
Sh. M. Nagi, É. A. Zubkov, V. G. Shubin, Nitration of aromatic compounds catalyzed by ZrO2/sulfate, Russian Chemical Bulletin,
1500-1502, 39(7), 1990.
for general and reliable informations on nitration i recommend reading chapter 7 of the book "chemistry of energetic materials". this chapter is written by nobel prize winner George A. OLAH. In general, all chapters in this book are interesting to read.
Dany.
Attachment: NITRATION OF AROMATIC COMPOUNDS CATALYZED BY ZrO2-SULFATE.pdf (227kB)
This file has been downloaded 605 times
[Edited on 11-1-2014 by Dany]
|
|
|
Pulverulescent
National Hazard
Posts: 793
Registered: 31-1-2008
Member Is Offline
Mood: Torn between two monikers ─ "hissingnoise" and the present incarnation!
|
|
| Quote: | | My question: does anyone now which journal Khim. is and where I could find it? |
It's; Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya.
Didn't find a site . . .
[edit] found it!
[Edited on 12-1-2014 by Pulverulescent]
"I know not with what weapons World War III will be fought, but World War IV will be fought with sticks and stones"
A Einstein
|
|
|
underground
National Hazard
Posts: 697
Registered: 10-10-2013
Location: Europe
Member Is Offline
|
|
How much does the addition of ZrO2 will going to help the nitration process ?? The yields are going to be better ?
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
