Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Formaldehyde disposal
ADP
Hazard to Others
***




Posts: 120
Registered: 4-4-2005
Location: USA
Member Is Offline

Mood: Productive

[*] posted on 10-11-2005 at 17:42
Formaldehyde disposal


Is formaldehyde oxidized by hydrogen peroxide to formic acid and is this means of safe disposal? I was thinking...

CH2O + H2O2 --> CHOOH + H2O

CHOOH + NaOH --> CHOONa + H2O

The remaining sodium formate could somehow be easier to dispose? What happens when a NaOH solution is added to a formaldehyde solution?
View user's profile View All Posts By User
mick
Hazard to Others
***




Posts: 338
Registered: 3-10-2003
Member Is Offline

Mood: No Mood

[*] posted on 11-11-2005 at 13:20


If formaldehyde and alkali is anything like acetaldehyde and alkali in water then you could end up with some plasticy stuff that still smells of the aldehyde, takes ages to set,still smells and sticks to everthing when finally drying out and setting. Acetone dissolved the residue.
I am not sure if this is right but I read that the reaction of formaldehyde and ammonia in the right quantities produces a good fertilizer. It certainly kills the smell of formaldehyde and probably makes it more biodegradable.
mick
View user's profile View All Posts By User
The_Davster
A pnictogen
*******




Posts: 2861
Registered: 18-11-2003
Member Is Offline

Mood: .

[*] posted on 11-11-2005 at 13:31


For disposal you could react with ammonia, allow water to evaporate off and then either keep the hexamine formed or just burn it, it is used as a camping fuel after all.



View user's profile View All Posts By User
hydrargirum
Harmless
*




Posts: 19
Registered: 14-6-2005
Location: chile
Member Is Offline

Mood: No Mood

[*] posted on 11-11-2005 at 18:34


Quote:

Whats happens when NaOH solution is added to a formaldehyde solution?

I have understood that HCHO reacts with solution of NaOH
according to:
2HCHO + NaOH ------> CH3OH + HCOONa
(Cannizzaro Reaction)
View user's profile View All Posts By User
ADP
Hazard to Others
***




Posts: 120
Registered: 4-4-2005
Location: USA
Member Is Offline

Mood: Productive

[*] posted on 12-11-2005 at 06:53


Thanks for the suggestions guys
View user's profile View All Posts By User

  Go To Top