Nitrogen dioxide

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Nitrogen dioxide
IMG 0171.JPG
Nitrogen dioxide(right) being generated by the reaction of copper metal with nitric acid.
Names
IUPAC name
Nitrogen dioxide
Other names
Deutoxide of nitrogen
Nitrogen(IV) oxide
Properties
NO2
Molar mass 46.0055 g/mol
Appearance Reddish-brown gas
Odor Car exhaustion-like
Density 1.88 g/l
Melting point −11.2 °C (11.8 °F; 261.9 K)
Boiling point 21.2 °C (70.2 °F; 294.3 K)
Reacts giving nitric acid and nitric oxide
Solubility Reacts with alcohols
Soluble in carbon tetrachloride, chloroform, nitric acid
Vapor pressure 98.80 kPa (at 20 °C)
Thermochemistry
240 J·mol-1·K-1
34 kJ/mol
Hazards
Safety data sheet Sigma-Aldrich
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
30 ppm (guinea pig, 1 hr)
315 ppm (rabbit, 15 min)
68 ppm (rat, 4 hr)
138 ppm (rat, 30 min)
1000 ppm (mouse, 10 min)
Related compounds
Related compounds
Nitric oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Nitrogen dioxide is inorganic compound, one of several oxides of nitrogen, with chemical formula NO2. It is an acutely toxic reddish-brown gas with a sharp smell and is a potent oxidizer. It is often utilized in the production of nitric acid.

Properties

Chemical

Contact between nitrogen dioxide and organic compounds(such as some plastics) can result in explosions, arising from its highly oxidative properties. The dissolution of nitrogen dioxide in water produces nitric acid along with short-lived nitrous acid. A higher yield of nitric acid is obtained if nitrogen dioxide is instead passed into hydrogen peroxide, though neither of these methods is the most efficient for producing nitric acid. Nitrogen dioxide can also be used to produce nitrate salts by passing it over a metal oxide.

Nitrogen dioxide is at equilibrium with dinitrogen tetroxide containing about 12% nitrogen dioxide and 88% dinitrogen tetroxide at STP.

Physical

Nitrogen dioxide appears as an amber-colored gas. It presents a very unique pungent odor in low concentrations, such as during its emission in car exhaust, but at high concentrations has a much sharper smell often accompanied by a painful or prickling sensation in the nose. Nitrogen dioxide boils at 21.2 °C and melts at −11.2 °C. It will react with water in the presence of an oxidizer to produce nitric acid. It is however, soluble in carbon tetrachloride and chloroform. Nitrogen dioxide is denser than air, and may accumulate in low areas without air flow.

Availability

Nitrogen dioxide must typically be produced in a lab setting, rather than purchased.

Preparation

Nitrogen dioxide is readily produced by reacting nitric acid with a number of metals, most notably copper, in a highly exothermic reaction, or by reacting a nitrate salt with hot or concentrated strong acids. It is also produced as a side-product of nitrations or when nitric acid is heated to the point of decomposition. Experiments involving the production of this gas should always be done in a reliable fume hood or outside.

Projects

Handling

Safety

Nitrogen dioxide is quite toxic and overexposure can lead to permanent injury or even death. Inhalation should always be kept to a minimum, and it is best to conduct experiments with nitrogen dioxide in a fume hood or outside and at a distance. Above certain concentrations in air, nitrogen dioxide anesthetizes the nose, making its detection by smell nearly impossible. Nitrogen dioxide readily attacks many kinds of plastics, including tubing, and can cause fires and explosions in this manner.

Storage

Nitrogen dioxide should only be stored when needed to perform a reaction and only for short periods of time. Since it boils at 21.2 °C, it is very easy to liquefy and can be stored in thick ampoules for display. However, due to its hazards, it's better to not store a larger quantity and should be made in situ when needed.

Disposal

Nitrogen dioxide can be neutralized by bubbling it through an alkali solution.

References

Relevant Sciencemadness threads