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Author: Subject: Telling if a reaction will occur
DalisAndy
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[*] posted on 30-7-2015 at 15:59
Telling if a reaction will occur


I was wondering how one would calculate if a reaction will take place? I have an AP Chem textbook. If that would help



Elements Collected: 19/81 (Excluding all radioactive, using placecard for those)

Any tips or good sources are welcome.
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blogfast25
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[*] posted on 30-7-2015 at 16:04


Have a look at this, just for starters:

http://hyperphysics.phy-astr.gsu.edu/hbase/chemical/gibbspon...

For ΔG < 0, a chemical reaction is thermodynamically favourable. That theory and the related theory of reaction kinetics are complex and cannot be summarised in a few sentences here.


[Edited on 31-7-2015 by blogfast25]




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diddi
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[*] posted on 30-7-2015 at 16:12


how about redox potentials?
for inorganics anyway :)




Beginning construction of periodic table display
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blogfast25
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[*] posted on 30-7-2015 at 16:16


Quote: Originally posted by diddi  
how about redox potentials?
for inorganics anyway :)


They only work in watery solutions. As such they are a 'special case' of chemical thermodynamics and kinetics.




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softbeard
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[*] posted on 30-7-2015 at 16:19


In general, a reaction has thermodynamic impetus to go forward if the equation's Gibbs Free Energy change (delta G) is negative (<0). But that's just thermodynamics. It says nothing about a reaction's kinetics which may be extremely slow and take a very long time before equilibrium is achieved.
Note that the delta G for a reaction may be a strong function of temperature, pressure (in the case of gases/vapours), or both. So it is very important you consider reaction conditions (eg. 273 Celcius, 1 atm.) while asking this question.
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