Potassium hexachlorostannate

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Potassium hexachlorostannate
IUPAC name
Potassium hexachlorostannate(IV)
Molar mass 409.605 g/mol
Appearance White solid
Density 2.719 g/cm3[1]
Melting point 300 °C (572 °F; 573 K) (decomposes)
Boiling point 520 °C (968 °F; 793 K) Decomposes
Solubility Soluble in liq. NH3
Insoluble in acetonitrile, conc. HCl, SnCl4
-1,483.8 kJ/kmol
Safety data sheet None
Flash point Non-flammable
Related compounds
Related compounds
Ammonium hexachlorostannate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Potassium hexachlorostannate is an inorganic chemical compound with the chemical formula K2SnCl6, used mainly for obtaining tin(IV) chloride.



Potassium hexachlorostannate is the salt of a strong acid and its solutions react neutral in water. Addition of alkali or ammonia solution precipitates Sn(OH)4·nH2O. Further addition of strong alkali causes soluble stannate (K2Sn(OH)6) to form.

On strong heating (> 300 °C, est.) it releases SnCl4 (b.p. 114.15 °C), so it affords a chlorine-free route to this useful chemical. The ammonium salt sublimes completely.


Potassium hexachlorostannate is a colorless crystalline solid.

It is insoluble in 37 w% HCl which offers an easy method of purifying the salt.

In literature, there are multiple values given for the melting and decomposition point of this compound: 409 °C[2], 470 °C[3], 520 °C[4], 760 °C[5]


It is not sold by most chemical entities and has to be prepared.


Potassium hexachlorostannate (IV) is prepared by dissolving tin metal (or pewter) in a mixture of nitric acid and hydrochloric acid (aqua regia). More or less stoichiometric amounts of the acids can be used in accordance with:

3 Sn(s) + 4 NO3-(aq) + 16 H+(aq) → 3 Sn4+(aq) + 4 NO(g) + 8 H2O(l)
3 Sn4+(aq) + 18 HCl(aq) → 3 SnCl62-(aq) + 18 H+(aq)

Dissolution is very swift and does not usually require heating.

Once complete the solution is brought to a gentle simmer and solid KCl is added, 2 mol per mol of tin. The mixture is then simmered and stirred until all the KCl is dissolved, then allowed to cool naturally, then further chilled on ice bath, e.g. overnight.

Well-formed crystals of K2SnCl6 are obtained.

Ammonium hexachlorostannate is obtained in identical conditions but by replacing KCl with NH4Cl.

Instead of pure tin, pewter (Sn/Sb alloy) can also be used because the corresponding Sb salt, KSbCl6 is very soluble even at low temperature and simply stays in solution.

The salts can also be obtained by oxidation of an SnCl2 solution in HCl, with hydrogen peroxide or nitric acid as oxidiser. Add KCl (or NH4Cl) as per above.


  • Make tin(IV) chloride



Potassium hexachlorostannate may be corrosive and should be handled with proper protection


In closed containers.


Should be disposed like any other tin compound.


  1. Vogt, K.; Reichardt, W.; Prandl, W.; Haussuehl, S.; Physica Status Solidi A: Applied Research; vol. 57; (1980); p. K145 - K148
  2. Yu, Jiang-Tsu; Wu, Ching-Jiun; Lou, Ssu-Hao; Tsai, Mei-Na; Journal of Solid State Chemistry; vol. 98; (1992); p. 159 - 173
  3. Janiak; Nikel; Blazejowski; Journal of thermal analysis; vol. 36; nb. 6; (1990); p. 2205 - 2210
  4. Volkov, V. V.; Myakishev, K. G.; Solomatina, L. Ya.; Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii); vol. 40; (1995); p. 1559 - 1562;
  5. Zalewicz, Malgorzata; Thermochimica Acta; vol. 116; (1987); p. 217 - 224

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