Difference between revisions of "Mercury(II) thiocyanate"

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| pKa =  
 
| pKa =  
 
| pKb =  
 
| pKb =  
| Solubility = 0.069 g/100 mL (at 25 ºC)
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| Solubility = 0.069 g/100 ml (at 25 ºC)
 
| SolubleOther = Soluble in dilute [[hydrochloric acid]], anhydrous [[ammonia]], KCN<br>Slightly soluble in [[ethanol]], [[diethyl ether]]
 
| SolubleOther = Soluble in dilute [[hydrochloric acid]], anhydrous [[ammonia]], KCN<br>Slightly soluble in [[ethanol]], [[diethyl ether]]
 
| Solvent =  
 
| Solvent =  
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'''Mercury(II) thiocyanate''' is an inorganic chemical compound with the chemical formula '''Hg(SCN)<sub>2</sub>'''. When ignited, it will produce a large, expanding “snake”, effect known as the [[Pharaoh’s serpent]].
+
'''Mercury(II) thiocyanate''' is an inorganic chemical compound with the chemical formula '''Hg(SCN)<sub>2</sub>'''. When ignited, it will produce a large, expanding “snake”, effect known as the [[Pharaoh's serpent]].
  
 
==Properties==
 
==Properties==
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===Physical===
 
===Physical===
Mercury(II) thiocyanate is a white solid, extremely poorly soluble in water, but somewhat soluble in other solvents and acids. It decomposes when heated above 165 °C. It's density at standard conditions is  
+
Mercury(II) thiocyanate is a white solid, extremely poorly soluble in water, but somewhat soluble in other solvents and acids. It decomposes when heated above 165 °C. Its density at standard conditions is 3.71 g/cm<sup>3</sup>.
  
 
==Availability==
 
==Availability==
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==Preparation==
 
==Preparation==
Mercury(II) thiocyanate can be made by reacting a soluble thiocyanate salt, such as potassium thiocynate with mercury(II) nitrate:
+
Mercury(II) thiocyanate can be made by reacting a soluble thiocyanate salt, such as [[potassium thiocynate]] with [[mercury(II) nitrate]]:
  
 
:Hg(NO<sub>3</sub>)<sub>2</sub> + 2 KSCN → Hg(SCN)<sub>2</sub> + 2 KNO<sub>3</sub>
 
:Hg(NO<sub>3</sub>)<sub>2</sub> + 2 KSCN → Hg(SCN)<sub>2</sub> + 2 KNO<sub>3</sub>
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==Handling==
 
==Handling==
 
===Safety===
 
===Safety===
Mercury(II) thiocyanate is very toxic and proper protection should be worn when handling the compound.
+
Mercury(II) thiocyanate is very toxic and proper protection must be worn when handling the compound.
  
 
===Storage===
 
===Storage===

Latest revision as of 12:13, 28 October 2017

Mercury(II) thiocyanate
Names
IUPAC name
Mercury(II) thiocyanate
Other names
Mercuric thiocyanate
Mercuric sulfocyanate
Identifiers
Jmol-3D images Image
Properties
Hg(SCN)2
Molar mass 316.755 g/mol
Appearance White solid
Density 3.71 g/cm3
Melting point 165 °C (329 °F; 438 K) (decomposes)
Boiling point Decomposes
0.069 g/100 ml (at 25 ºC)
Solubility Soluble in dilute hydrochloric acid, anhydrous ammonia, KCN
Slightly soluble in ethanol, diethyl ether
Hazards
Safety data sheet ScienceLab
Flash point 121 ºC
Lethal dose or concentration (LD, LC):
46 mg/kg (rat, oral)
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Mercury(II) thiocyanate is an inorganic chemical compound with the chemical formula Hg(SCN)2. When ignited, it will produce a large, expanding “snake”, effect known as the Pharaoh's serpent.

Properties

Chemical

When ignited, mercury thiocyanate will decompose into an expanding residue, which has the form of a snake. The thermal decomposition is fairly complex and occurs in several stages:

2 Hg(SCN)2 → 2 HgS + CS2 + C3N4
CS2 + 3O2 → CO2 + 2 SO2
2 C3N4 → 3 (CN)2 + N2
HgS + O2 → Hg + SO2

Physical

Mercury(II) thiocyanate is a white solid, extremely poorly soluble in water, but somewhat soluble in other solvents and acids. It decomposes when heated above 165 °C. Its density at standard conditions is 3.71 g/cm3.

Availability

Mercury thiocyanate is sold by various chemical suppliers. It is sometimes sold on eBay.

Being a mercury compound, the sale of this compound is regulated in most countries.

Preparation

Mercury(II) thiocyanate can be made by reacting a soluble thiocyanate salt, such as potassium thiocynate with mercury(II) nitrate:

Hg(NO3)2 + 2 KSCN → Hg(SCN)2 + 2 KNO3

Since Hg(SCN)2 is sparingly soluble in water, it will precipitate. Filter the precipitate and dry it, preferably in open air or in a desiccator. Avoid strong heat, as it cause it to decompose.

Projects

  • Pharaoh’s serpent

Handling

Safety

Mercury(II) thiocyanate is very toxic and proper protection must be worn when handling the compound.

Storage

Mercury(II) thiocyanate should be kept in a closed bottle, away from corrosive vapors. DO NOT STORE IT IN ALUMINIUM CONTAINERS!

Disposal

Mercury(II) thiocyanate can be neutralized by turning it into mercury sulfide HgS, which is much less toxic. It then should be taken to special disposal centers.

References

Relevant Sciencemadness threads