Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Arrhenius equation help plz
yoyoils
Harmless
*




Posts: 22
Registered: 6-8-2011
Member Is Offline

Mood: positive

[*] posted on 20-8-2011 at 02:30
Arrhenius equation help plz


Could someone please help me with this
http://www.chemicalforums.com/index.php?topic=50712.msg188910#msg188910

p.s I apologize for it being a link to another chemistry forum, im just really desperate because this is holding me up a lot of time, if it breaks any rules or if you don't like it i'll delete this.

[Edited on 20-8-2011 by yoyoils]




View user's profile View All Posts By User
blogfast25
International Hazard
*****




Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline

Mood: No Mood

[*] posted on 20-8-2011 at 05:22


This really belongs in the 'Beginners section'.

Your question isn't clear though.

Try first to understand the concept of Arrhenius' Lawn (you need to understand Collision Theory for that):


http://en.wikipedia.org/wiki/Arrhenius_equation

Then maybe ask a concise question, one to which an answer exists?




View user's profile View All Posts By User
yoyoils
Harmless
*




Posts: 22
Registered: 6-8-2011
Member Is Offline

Mood: positive

[*] posted on 20-8-2011 at 10:28


I just need to know how to literally use the calculator to get the answers to Arrhenius equation.

question:
k = 1014 * e(-58400 cal/mol /(1.986 cal/K mol * 773 K))

like for example: pressing the following buttons:

[1][.][9][8][6] times [7][7][3] = 1535.178
[STO][1]

[5][8][4][0][0][+-] divided by [RCL][1] = -38.04119131

would someone please tell me what i'm supposed to type in next to answer this with my calculator

the answer is supposedly = 3.01*10-17 but i need to know how to get that

[Edited on 20-8-2011 by yoyoils]




View user's profile View All Posts By User
blogfast25
International Hazard
*****




Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline

Mood: No Mood

[*] posted on 20-8-2011 at 11:58


Depends on your calculator:

Try:

-38.04119131, SHIFT (or INV), ln x

Or, for more modern calculators:

SHIFT (or INV), ln x, -38.04119131
(in the latter case you may have to put the number between backets ( and ) ) Commas here used to separate keystrokes.

Then multiply with 1014. The answer is 3.0546 x 10<sup>-14</sup>




View user's profile View All Posts By User
yoyoils
Harmless
*




Posts: 22
Registered: 6-8-2011
Member Is Offline

Mood: positive

[*] posted on 20-8-2011 at 19:59


I'm using this calculator now bcuz I found out mines too old http://web2.0calc.com/

I put in: 10^14 * e(-38.04119131) and it = 3.01245472874 which is 3.012 x 10^-3

but I'm still worried if that's not accurate enough because my book states:

k = 10^14 e -58.4/1.53 = 3.03 x 10^-3 s-1

[Edited on 21-8-2011 by yoyoils]




View user's profile View All Posts By User
blogfast25
International Hazard
*****




Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline

Mood: No Mood

[*] posted on 21-8-2011 at 04:55


Quote: Originally posted by yoyoils  
I'm using this calculator now bcuz I found out mines too old http://web2.0calc.com/

I put in: 10^14 * e(-38.04119131) and it = 3.01245472874 which is 3.012 x 10^-3

but I'm still worried if that's not accurate enough because my book states:

k = 10^14 e -58.4/1.53 = 3.03 x 10^-3 s-1

[Edited on 21-8-2011 by yoyoils]


Which is it (LOL)?

1014 * e(-58400 cal/mol /(1.986 cal/K mol * 773 K)) ??

or

10^14 * e(-58400 cal/mol /(1.986 cal/K mol * 773 K)) ??

Well, 10<sup>14</sup> x e<sup>(-58400 cal/mol /(1.986 cal/K mol * 773 K)</sup> = 3.012 x 10<sup>-3</sup> = 0.003012 s<sup>-1</sup>

At least it's a plausible sounding value...:cool:

That web calculator is pretty useless, BTW. It didn't even convert e<sup>-30.04</sup> to the exponential format (10<sup>somenumber</sup>;)! That thing is OK for basic calculations but not much more.

Try the calculator that comes with windows, that's not too bad...




[Edited on 21-8-2011 by blogfast25]




View user's profile View All Posts By User

  Go To Top