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An aldehyde or alkanal, is an organic compound containing a functional group with the structure −CHO (or -CH=O), consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen, and to an R group, which is any generic alkyl or side chain, or some inorganic group (H, halogen, CF3, etc.).
Aldehydes are volatile compounds, with a strong smell. They are flammable and react with bases, both metal hydroxides and amines, reaction which releases lots of heat. Aldehydes degrade in air via the process of autoxidation, forming various polymers.
Aldehydes characteristically form "addition compounds" with sodium bisulfite.
Many high weight aldehydes (benzaldehyde, cinnamaldehyde, etc) have strong and pleasant smells.
Aldehydes can be easily prepared through the Jones oxidation of primary alcohols, which consists of chromium trioxide or potassium dichromate dissolved in a mixture of acetone and dilute sulfuric acid.
Chromium-free oxidation routes involve 2-iodoxybenzoic acid (IBX acid), Dess–Martin periodinane, Swern oxidation, TEMPO, or the Oppenauer oxidation.
Aldehydes can also be produced by oxidizing primary alcohols through near red hot copper. This method is simple enough that can be used to produce large amounts of aldehyde in a lab setting.
Industrially aldehydes are prepared via hydroformylation of alkenes.
- Ca(HCOO)2 → CH2O + CaCO3
Low weight aldehydes are toxic and carcinogenic. Some may form peroxides upon prolonged contact with air.